1-(Isopropylideneamino)guanidinium 2-nitrobenzoate: formation of corrugated sheets from R-2(2)(8) and R-6(4)(16) rings

Jan Skakle, James L. Wardell, Solange M. S. V. Wardell

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

In the title compound, C4H11N4+center dot C7H4NO4-, the guanidinium cation acts as a strong hydrogen-bonding donor via the guanidine NH2 and NH groups, with the carboxy groups of the nitrobenzoate group acting as the acceptors. These hydrogen bonds lead to fused R-2(2)(8) and R-6(4)(16) rings, which form corrugated sheets perpendicular to [010].

Original languageEnglish
Pages (from-to)O476-O477
Number of pages2
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume62
DOIs
Publication statusPublished - 2006

Fingerprint

Guanidine
Hydrogen bonds
Nitrobenzoates
Hydrogen Bonding
Cations
Hydrogen
rifazone-82
2-nitrobenzoate

Keywords

  • o-hydrogen bonds
  • center-dot-O

Cite this

1-(Isopropylideneamino)guanidinium 2-nitrobenzoate : formation of corrugated sheets from R-2(2)(8) and R-6(4)(16) rings. / Skakle, Jan; Wardell, James L.; Wardell, Solange M. S. V.

In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. 62, 2006, p. O476-O477.

Research output: Contribution to journalArticle

@article{6990c5aa6bd84341bd0c4bf27dd56fa4,
title = "1-(Isopropylideneamino)guanidinium 2-nitrobenzoate: formation of corrugated sheets from R-2(2)(8) and R-6(4)(16) rings",
abstract = "In the title compound, C4H11N4+center dot C7H4NO4-, the guanidinium cation acts as a strong hydrogen-bonding donor via the guanidine NH2 and NH groups, with the carboxy groups of the nitrobenzoate group acting as the acceptors. These hydrogen bonds lead to fused R-2(2)(8) and R-6(4)(16) rings, which form corrugated sheets perpendicular to [010].",
keywords = "o-hydrogen bonds, center-dot-O",
author = "Jan Skakle and Wardell, {James L.} and Wardell, {Solange M. S. V.}",
year = "2006",
doi = "10.1107/S0108270106020580",
language = "English",
volume = "62",
pages = "O476--O477",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",

}

TY - JOUR

T1 - 1-(Isopropylideneamino)guanidinium 2-nitrobenzoate

T2 - formation of corrugated sheets from R-2(2)(8) and R-6(4)(16) rings

AU - Skakle, Jan

AU - Wardell, James L.

AU - Wardell, Solange M. S. V.

PY - 2006

Y1 - 2006

N2 - In the title compound, C4H11N4+center dot C7H4NO4-, the guanidinium cation acts as a strong hydrogen-bonding donor via the guanidine NH2 and NH groups, with the carboxy groups of the nitrobenzoate group acting as the acceptors. These hydrogen bonds lead to fused R-2(2)(8) and R-6(4)(16) rings, which form corrugated sheets perpendicular to [010].

AB - In the title compound, C4H11N4+center dot C7H4NO4-, the guanidinium cation acts as a strong hydrogen-bonding donor via the guanidine NH2 and NH groups, with the carboxy groups of the nitrobenzoate group acting as the acceptors. These hydrogen bonds lead to fused R-2(2)(8) and R-6(4)(16) rings, which form corrugated sheets perpendicular to [010].

KW - o-hydrogen bonds

KW - center-dot-O

U2 - 10.1107/S0108270106020580

DO - 10.1107/S0108270106020580

M3 - Article

VL - 62

SP - O476-O477

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -