1,4-diazoniabicyclo[2.2.2]octane triapuatrichloronickelate(II) chloride monohydrate

C A Bremner, W T A Harrison

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The title compound, (C6H14N2)[NiCl3(H2O)(3)]Cl.H2O, contains doubly protonated 1,4-diazoniabicyclo[2.2.2] octane (dabconium) (C6H14N2)(2+) cations, mer-[Ni-II(H2O)(3)Cl-3](-) octahedra, [mean Ni-O = 2.054 (2) Angstrom and mean Ni-Cl = 2.4272 (6) Angstrom] and additional (non-coordinated) chloride ions and water molecules. These species interact by way of numerous O - H...O, O - H...Cl and N - H...Cl hydrogen bonds and possible C - H...Cl interactions [mean H...Cl = 2.75 Angstrom, mean C...Cl = 3.575 (3) Angstrom and mean C - H...Cl = 142degrees] to result in a structure with a layered character. (C6H14N2)[Ni(H2O)(3)Cl-3]Cl.H2O is isostructural with its manganese(II)-containing congener.

Original languageEnglish
Pages (from-to)m797-m799
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
VolumeE59
DOIs
Publication statusPublished - 2003

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octanes
Manganese
Cations
Chlorides
Hydrogen bonds
Positive ions
chlorides
Ions
Molecules
Water
congeners
manganese
octane
hydrogen bonds
cations
water
molecules
ions
interactions

Keywords

  • crystal-structure
  • thermal-behaviour

Cite this

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title = "1,4-diazoniabicyclo[2.2.2]octane triapuatrichloronickelate(II) chloride monohydrate",
abstract = "The title compound, (C6H14N2)[NiCl3(H2O)(3)]Cl.H2O, contains doubly protonated 1,4-diazoniabicyclo[2.2.2] octane (dabconium) (C6H14N2)(2+) cations, mer-[Ni-II(H2O)(3)Cl-3](-) octahedra, [mean Ni-O = 2.054 (2) Angstrom and mean Ni-Cl = 2.4272 (6) Angstrom] and additional (non-coordinated) chloride ions and water molecules. These species interact by way of numerous O - H...O, O - H...Cl and N - H...Cl hydrogen bonds and possible C - H...Cl interactions [mean H...Cl = 2.75 Angstrom, mean C...Cl = 3.575 (3) Angstrom and mean C - H...Cl = 142degrees] to result in a structure with a layered character. (C6H14N2)[Ni(H2O)(3)Cl-3]Cl.H2O is isostructural with its manganese(II)-containing congener.",
keywords = "crystal-structure, thermal-behaviour",
author = "Bremner, {C A} and Harrison, {W T A}",
year = "2003",
doi = "10.1107/S1600536803018555",
language = "English",
volume = "E59",
pages = "m797--m799",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",

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TY - JOUR

T1 - 1,4-diazoniabicyclo[2.2.2]octane triapuatrichloronickelate(II) chloride monohydrate

AU - Bremner, C A

AU - Harrison, W T A

PY - 2003

Y1 - 2003

N2 - The title compound, (C6H14N2)[NiCl3(H2O)(3)]Cl.H2O, contains doubly protonated 1,4-diazoniabicyclo[2.2.2] octane (dabconium) (C6H14N2)(2+) cations, mer-[Ni-II(H2O)(3)Cl-3](-) octahedra, [mean Ni-O = 2.054 (2) Angstrom and mean Ni-Cl = 2.4272 (6) Angstrom] and additional (non-coordinated) chloride ions and water molecules. These species interact by way of numerous O - H...O, O - H...Cl and N - H...Cl hydrogen bonds and possible C - H...Cl interactions [mean H...Cl = 2.75 Angstrom, mean C...Cl = 3.575 (3) Angstrom and mean C - H...Cl = 142degrees] to result in a structure with a layered character. (C6H14N2)[Ni(H2O)(3)Cl-3]Cl.H2O is isostructural with its manganese(II)-containing congener.

AB - The title compound, (C6H14N2)[NiCl3(H2O)(3)]Cl.H2O, contains doubly protonated 1,4-diazoniabicyclo[2.2.2] octane (dabconium) (C6H14N2)(2+) cations, mer-[Ni-II(H2O)(3)Cl-3](-) octahedra, [mean Ni-O = 2.054 (2) Angstrom and mean Ni-Cl = 2.4272 (6) Angstrom] and additional (non-coordinated) chloride ions and water molecules. These species interact by way of numerous O - H...O, O - H...Cl and N - H...Cl hydrogen bonds and possible C - H...Cl interactions [mean H...Cl = 2.75 Angstrom, mean C...Cl = 3.575 (3) Angstrom and mean C - H...Cl = 142degrees] to result in a structure with a layered character. (C6H14N2)[Ni(H2O)(3)Cl-3]Cl.H2O is isostructural with its manganese(II)-containing congener.

KW - crystal-structure

KW - thermal-behaviour

U2 - 10.1107/S1600536803018555

DO - 10.1107/S1600536803018555

M3 - Article

VL - E59

SP - m797-m799

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

ER -