2-Benzylamino-6-benzyloxypyrimidin-4(3H)-one: hydrogen-bonded chains of rings linked into sheets by a p-p-stacking interaction

A. Quesada, M. Melguizo, C. Glidewell

    Research output: Contribution to journalArticle

    Abstract

    The title compound, C18H17N3O2, crystallizes with Z' = 2 in space group P2(1)/c, and the two independent molecules are approximate, but not exact, mirror images. The molecular-electronic structure is strongly polarized, and the molecules are linked by paired N-H...O hydrogen bonds [H...O = 2.00-2.23 Angstrom, N...O = 2.798 (3)-2.992 (3) Angstrom and N-H...O = 145-151degrees] into two independent C(4)C(6)[R-2(1)(6)] chains of rings, which are linked into sheets by a single aromatic pi-pi-stacking interaction.

    Original languageEnglish
    Pages (from-to)o400-o402
    Number of pages3
    JournalActa Crystallographica Section C, Crystal Structure Communications
    VolumeC59
    DOIs
    Publication statusPublished - 2003

    Cite this

    2-Benzylamino-6-benzyloxypyrimidin-4(3H)-one: hydrogen-bonded chains of rings linked into sheets by a p-p-stacking interaction. / Quesada, A.; Melguizo, M.; Glidewell, C.

    In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. C59, 2003, p. o400-o402.

    Research output: Contribution to journalArticle

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    abstract = "The title compound, C18H17N3O2, crystallizes with Z' = 2 in space group P2(1)/c, and the two independent molecules are approximate, but not exact, mirror images. The molecular-electronic structure is strongly polarized, and the molecules are linked by paired N-H...O hydrogen bonds [H...O = 2.00-2.23 Angstrom, N...O = 2.798 (3)-2.992 (3) Angstrom and N-H...O = 145-151degrees] into two independent C(4)C(6)[R-2(1)(6)] chains of rings, which are linked into sheets by a single aromatic pi-pi-stacking interaction.",
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    T1 - 2-Benzylamino-6-benzyloxypyrimidin-4(3H)-one: hydrogen-bonded chains of rings linked into sheets by a p-p-stacking interaction

    AU - Quesada, A.

    AU - Melguizo, M.

    AU - Glidewell, C.

    PY - 2003

    Y1 - 2003

    N2 - The title compound, C18H17N3O2, crystallizes with Z' = 2 in space group P2(1)/c, and the two independent molecules are approximate, but not exact, mirror images. The molecular-electronic structure is strongly polarized, and the molecules are linked by paired N-H...O hydrogen bonds [H...O = 2.00-2.23 Angstrom, N...O = 2.798 (3)-2.992 (3) Angstrom and N-H...O = 145-151degrees] into two independent C(4)C(6)[R-2(1)(6)] chains of rings, which are linked into sheets by a single aromatic pi-pi-stacking interaction.

    AB - The title compound, C18H17N3O2, crystallizes with Z' = 2 in space group P2(1)/c, and the two independent molecules are approximate, but not exact, mirror images. The molecular-electronic structure is strongly polarized, and the molecules are linked by paired N-H...O hydrogen bonds [H...O = 2.00-2.23 Angstrom, N...O = 2.798 (3)-2.992 (3) Angstrom and N-H...O = 145-151degrees] into two independent C(4)C(6)[R-2(1)(6)] chains of rings, which are linked into sheets by a single aromatic pi-pi-stacking interaction.

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    DO - 10.1107/S0108270103011132

    M3 - Article

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    JO - Acta Crystallographica Section C, Crystal Structure Communications

    JF - Acta Crystallographica Section C, Crystal Structure Communications

    SN - 0108-2701

    ER -