2-Nitrophenoxyacetanilide: a chain of rings generated by C-H center dot center dot center dot O hydrogen bonds

C Glidewell, J N Low, J M S Skakle, J L Wardell

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Abstract

In molecules of the title compound, C14H12N2O4, the conformation is dominated by an intramolecular N-H...O hydrogen bond in which one of the nitro O atoms is the acceptor. The molecules are linked by paired C-H...O hydrogen bonds [H...O = 2.41 Angstrom, C...O = 3.2990 (17) Angstrom and C-H...O = 156degrees] into centrosymmetric R-2(2)(14) dimers; these dimers are linked weakly into chains of alternating R-2(2)(14) and R-4(4)(40) rings by a second C-H...O hydrogen bond [H...O = 2.55 Angstrom, C...O = 3.5006 (15) Angstrom and C-H...O = 162degrees].

Original languageEnglish
Number of pages3
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume60
DOIs
Publication statusPublished - 2004

Keywords

  • CRYSTALS

Cite this

@article{b6961d1deafb40c498ef67eaad8a7059,
title = "2-Nitrophenoxyacetanilide: a chain of rings generated by C-H center dot center dot center dot O hydrogen bonds",
abstract = "In molecules of the title compound, C14H12N2O4, the conformation is dominated by an intramolecular N-H...O hydrogen bond in which one of the nitro O atoms is the acceptor. The molecules are linked by paired C-H...O hydrogen bonds [H...O = 2.41 Angstrom, C...O = 3.2990 (17) Angstrom and C-H...O = 156degrees] into centrosymmetric R-2(2)(14) dimers; these dimers are linked weakly into chains of alternating R-2(2)(14) and R-4(4)(40) rings by a second C-H...O hydrogen bond [H...O = 2.55 Angstrom, C...O = 3.5006 (15) Angstrom and C-H...O = 162degrees].",
keywords = "CRYSTALS",
author = "C Glidewell and Low, {J N} and Skakle, {J M S} and Wardell, {J L}",
year = "2004",
doi = "10.1107/S010827010400513X",
language = "English",
volume = "60",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",

}

TY - JOUR

T1 - 2-Nitrophenoxyacetanilide: a chain of rings generated by C-H center dot center dot center dot O hydrogen bonds

AU - Glidewell, C

AU - Low, J N

AU - Skakle, J M S

AU - Wardell, J L

PY - 2004

Y1 - 2004

N2 - In molecules of the title compound, C14H12N2O4, the conformation is dominated by an intramolecular N-H...O hydrogen bond in which one of the nitro O atoms is the acceptor. The molecules are linked by paired C-H...O hydrogen bonds [H...O = 2.41 Angstrom, C...O = 3.2990 (17) Angstrom and C-H...O = 156degrees] into centrosymmetric R-2(2)(14) dimers; these dimers are linked weakly into chains of alternating R-2(2)(14) and R-4(4)(40) rings by a second C-H...O hydrogen bond [H...O = 2.55 Angstrom, C...O = 3.5006 (15) Angstrom and C-H...O = 162degrees].

AB - In molecules of the title compound, C14H12N2O4, the conformation is dominated by an intramolecular N-H...O hydrogen bond in which one of the nitro O atoms is the acceptor. The molecules are linked by paired C-H...O hydrogen bonds [H...O = 2.41 Angstrom, C...O = 3.2990 (17) Angstrom and C-H...O = 156degrees] into centrosymmetric R-2(2)(14) dimers; these dimers are linked weakly into chains of alternating R-2(2)(14) and R-4(4)(40) rings by a second C-H...O hydrogen bond [H...O = 2.55 Angstrom, C...O = 3.5006 (15) Angstrom and C-H...O = 162degrees].

KW - CRYSTALS

U2 - 10.1107/S010827010400513X

DO - 10.1107/S010827010400513X

M3 - Article

VL - 60

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -