2,6-Bis(phenylamino)-4-(iminophenyl)benzoquinone

M. John Plater

doi:10.3390/M1406

2,6-Bis(phenylamino)-4-(iminophenyl)benzoquinone

M. John Plater^* (Corresponding Author)

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

3 Downloads (Pure)

Abstract

The reaction of 2,4-difluoronitrobenzene with an excess of aniline at 175 °C led to the isolation of an unexpected brown quinone substituted with two phenylamino groups and one phenylimino group. This product was easily distinguished from other expected derivatives because it is brown rather than yellow. The UV/Vis has a weak long wavelength absorption at 480–600 nm accounting for the colour.

Original language	English
Article number	M1406
Number of pages	5
Journal	MolBank
Volume	2022
Issue number	3
Early online date	7 Jul 2022
DOIs	https://doi.org/10.3390/M1406
Publication status	Published - 7 Jul 2022

Bibliographical note

Funding: This research received no external funding
Acknowledgments: The University of Aberdeen Development Trust for funding.

Keywords

aniline
nitrobenzene
2,4-difluoronitrobenzene
Irgacure PAG 103

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10.3390/M1406Licence: CC BY

Plater_etal_MDPI_2_Bis(phenylamino_VoR_
© 2022 by the author. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/ 4.0/).
Final published version, 535 KBLicence: CC BY

Cite this

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title = "2,6-Bis(phenylamino)-4-(iminophenyl)benzoquinone",

abstract = "The reaction of 2,4-difluoronitrobenzene with an excess of aniline at 175 °C led to the isolation of an unexpected brown quinone substituted with two phenylamino groups and one phenylimino group. This product was easily distinguished from other expected derivatives because it is brown rather than yellow. The UV/Vis has a weak long wavelength absorption at 480–600 nm accounting for the colour.",

keywords = "aniline, nitrobenzene, 2,4-difluoronitrobenzene, Irgacure PAG 103",

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AU - Plater, M. John

N1 - Funding: This research received no external funding Acknowledgments: The University of Aberdeen Development Trust for funding.

PY - 2022/7/7

Y1 - 2022/7/7

N2 - The reaction of 2,4-difluoronitrobenzene with an excess of aniline at 175 °C led to the isolation of an unexpected brown quinone substituted with two phenylamino groups and one phenylimino group. This product was easily distinguished from other expected derivatives because it is brown rather than yellow. The UV/Vis has a weak long wavelength absorption at 480–600 nm accounting for the colour.

AB - The reaction of 2,4-difluoronitrobenzene with an excess of aniline at 175 °C led to the isolation of an unexpected brown quinone substituted with two phenylamino groups and one phenylimino group. This product was easily distinguished from other expected derivatives because it is brown rather than yellow. The UV/Vis has a weak long wavelength absorption at 480–600 nm accounting for the colour.

KW - aniline

KW - nitrobenzene

KW - 2,4-difluoronitrobenzene

KW - Irgacure PAG 103

U2 - 10.3390/M1406

DO - 10.3390/M1406

M3 - Article

SN - 1422-8599

VL - 2022

JO - MolBank

JF - MolBank

IS - 3

M1 - M1406

ER -

2,6-Bis(phenylamino)-4-(iminophenyl)benzoquinone

Abstract

Bibliographical note

Keywords

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