2,6-Diiodo-4-nitrophenol, 2,6-diiodo-4-nitrophenyl acetate and 2,6-diiodo-4-nitroanisole: interplay of hydrogen bonds, iodo-nitro interactions and aromatic [pi]-[pi]-stacking interactions to give supramolecular structures in one, two and three dimensions

S J Garden, F R da Cunha, J L Wardell, J M S Skakle, J N Low, C Glidewell

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Abstract

In 2,6-diiodo-4-nitrophenol, C6H3I2NO3, the molecules are linked, by an O-H...O hydrogen bond and two iodo-nitro interactions, into sheets, which are further linked into a three-dimensional framework by aromatic pi-pi-stacking interactions. The molecules of 2,6-diiodo-4-nitrophenyl acetate, C8H5I2NO4, lie across a mirror plane in space group Pnma, with the acetyl group on the mirror, and they are linked by a single iodo-nitro interaction to form isolated sheets. The molecules of 2,6-diiodo-4-nitroanisole, C7H5I2NO3, are linked into isolated chains by a single two-centre iodo-nitro interaction.

Original languageEnglish
Pages (from-to)o463-o466
Number of pages4
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume58
Issue number8
DOIs
Publication statusPublished - Aug 2002

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Hydrogen
Hydrogen bonds
Molecules
Mirrors
disophenol
4-nitroanisole
4-nitrophenyl acetate

Keywords

  • crystals

Cite this

@article{a50b372e4e3b4a41b2a6d867dc488ca7,
title = "2,6-Diiodo-4-nitrophenol, 2,6-diiodo-4-nitrophenyl acetate and 2,6-diiodo-4-nitroanisole: interplay of hydrogen bonds, iodo-nitro interactions and aromatic [pi]-[pi]-stacking interactions to give supramolecular structures in one, two and three dimensions",
abstract = "In 2,6-diiodo-4-nitrophenol, C6H3I2NO3, the molecules are linked, by an O-H...O hydrogen bond and two iodo-nitro interactions, into sheets, which are further linked into a three-dimensional framework by aromatic pi-pi-stacking interactions. The molecules of 2,6-diiodo-4-nitrophenyl acetate, C8H5I2NO4, lie across a mirror plane in space group Pnma, with the acetyl group on the mirror, and they are linked by a single iodo-nitro interaction to form isolated sheets. The molecules of 2,6-diiodo-4-nitroanisole, C7H5I2NO3, are linked into isolated chains by a single two-centre iodo-nitro interaction.",
keywords = "crystals",
author = "Garden, {S J} and {da Cunha}, {F R} and Wardell, {J L} and Skakle, {J M S} and Low, {J N} and C Glidewell",
year = "2002",
month = "8",
doi = "10.1107/S0108270102010776",
language = "English",
volume = "58",
pages = "o463--o466",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",
number = "8",

}

TY - JOUR

T1 - 2,6-Diiodo-4-nitrophenol, 2,6-diiodo-4-nitrophenyl acetate and 2,6-diiodo-4-nitroanisole: interplay of hydrogen bonds, iodo-nitro interactions and aromatic [pi]-[pi]-stacking interactions to give supramolecular structures in one, two and three dimensions

AU - Garden, S J

AU - da Cunha, F R

AU - Wardell, J L

AU - Skakle, J M S

AU - Low, J N

AU - Glidewell, C

PY - 2002/8

Y1 - 2002/8

N2 - In 2,6-diiodo-4-nitrophenol, C6H3I2NO3, the molecules are linked, by an O-H...O hydrogen bond and two iodo-nitro interactions, into sheets, which are further linked into a three-dimensional framework by aromatic pi-pi-stacking interactions. The molecules of 2,6-diiodo-4-nitrophenyl acetate, C8H5I2NO4, lie across a mirror plane in space group Pnma, with the acetyl group on the mirror, and they are linked by a single iodo-nitro interaction to form isolated sheets. The molecules of 2,6-diiodo-4-nitroanisole, C7H5I2NO3, are linked into isolated chains by a single two-centre iodo-nitro interaction.

AB - In 2,6-diiodo-4-nitrophenol, C6H3I2NO3, the molecules are linked, by an O-H...O hydrogen bond and two iodo-nitro interactions, into sheets, which are further linked into a three-dimensional framework by aromatic pi-pi-stacking interactions. The molecules of 2,6-diiodo-4-nitrophenyl acetate, C8H5I2NO4, lie across a mirror plane in space group Pnma, with the acetyl group on the mirror, and they are linked by a single iodo-nitro interaction to form isolated sheets. The molecules of 2,6-diiodo-4-nitroanisole, C7H5I2NO3, are linked into isolated chains by a single two-centre iodo-nitro interaction.

KW - crystals

U2 - 10.1107/S0108270102010776

DO - 10.1107/S0108270102010776

M3 - Article

VL - 58

SP - o463-o466

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

IS - 8

ER -