3-benzoyl-1,2,4,5-tetraphenylpentane-1.5-dione.

A molecular paddlewheel

B W Freer, R A Howie, O C Musgrave, J M S Skakle

Research output: Contribution to journalArticle

Abstract

Racemic (2R,4R)-, (2S,4S)-3-benzoyl-1,2,4,5-tetraphenylpentane-1,5-dione results from the alkali-induced condensation of acetophenone with desoxybenzoin in the presence of air. The structure which resembles that of an irregular five-bladed paddlewheel is confirmed by X-ray crystallography. (C) 2003 Elsevier Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)7385-7388
Number of pages4
JournalTetrahedron
Volume59
Issue number59
DOIs
Publication statusPublished - 8 Sep 2003

Fingerprint

X ray crystallography
X Ray Crystallography
Alkalies
Condensation
Air
acetophenone

Keywords

  • ketone
  • autoxidation
  • condensations
  • trione
  • X-ray crystal structure

Cite this

3-benzoyl-1,2,4,5-tetraphenylpentane-1.5-dione. A molecular paddlewheel. / Freer, B W ; Howie, R A ; Musgrave, O C ; Skakle, J M S .

In: Tetrahedron, Vol. 59, No. 59, 08.09.2003, p. 7385-7388.

Research output: Contribution to journalArticle

Freer, B W ; Howie, R A ; Musgrave, O C ; Skakle, J M S . / 3-benzoyl-1,2,4,5-tetraphenylpentane-1.5-dione. A molecular paddlewheel. In: Tetrahedron. 2003 ; Vol. 59, No. 59. pp. 7385-7388.
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