3-benzoyl-1,2,4,5-tetraphenylpentane-1.5-dione.: A molecular paddlewheel

B W  Freer; R A  Howie; O C  Musgrave; J M S  Skakle

doi:10.1016/S0040-4020(03)01147-5

3-benzoyl-1,2,4,5-tetraphenylpentane-1.5-dione. A molecular paddlewheel

B W Freer, R A Howie, O C Musgrave, J M S Skakle

Research output: Contribution to journal › Article › peer-review

Abstract

Racemic (2R,4R)-, (2S,4S)-3-benzoyl-1,2,4,5-tetraphenylpentane-1,5-dione results from the alkali-induced condensation of acetophenone with desoxybenzoin in the presence of air. The structure which resembles that of an irregular five-bladed paddlewheel is confirmed by X-ray crystallography. (C) 2003 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	7385-7388
Number of pages	4
Journal	Tetrahedron
Volume	59
Issue number	59
DOIs	https://doi.org/10.1016/S0040-4020(03)01147-5
Publication status	Published - 8 Sept 2003

Keywords

ketone
autoxidation
condensations
trione
X-ray crystal structure

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10.1016/S0040-4020(03)01147-5

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title = "3-benzoyl-1,2,4,5-tetraphenylpentane-1.5-dione.: A molecular paddlewheel",

abstract = "Racemic (2R,4R)-, (2S,4S)-3-benzoyl-1,2,4,5-tetraphenylpentane-1,5-dione results from the alkali-induced condensation of acetophenone with desoxybenzoin in the presence of air. The structure which resembles that of an irregular five-bladed paddlewheel is confirmed by X-ray crystallography. (C) 2003 Elsevier Ltd. All rights reserved.",

keywords = "ketone, autoxidation, condensations, trione, X-ray crystal structure",

author = "Freer, {B W} and Howie, {R A} and Musgrave, {O C} and Skakle, {J M S}",

year = "2003",

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T1 - 3-benzoyl-1,2,4,5-tetraphenylpentane-1.5-dione.

T2 - A molecular paddlewheel

AU - Freer, B W

AU - Howie, R A

AU - Musgrave, O C

AU - Skakle, J M S

PY - 2003/9/8

Y1 - 2003/9/8

N2 - Racemic (2R,4R)-, (2S,4S)-3-benzoyl-1,2,4,5-tetraphenylpentane-1,5-dione results from the alkali-induced condensation of acetophenone with desoxybenzoin in the presence of air. The structure which resembles that of an irregular five-bladed paddlewheel is confirmed by X-ray crystallography. (C) 2003 Elsevier Ltd. All rights reserved.

AB - Racemic (2R,4R)-, (2S,4S)-3-benzoyl-1,2,4,5-tetraphenylpentane-1,5-dione results from the alkali-induced condensation of acetophenone with desoxybenzoin in the presence of air. The structure which resembles that of an irregular five-bladed paddlewheel is confirmed by X-ray crystallography. (C) 2003 Elsevier Ltd. All rights reserved.

KW - ketone

KW - autoxidation

KW - condensations

KW - trione

KW - X-ray crystal structure

U2 - 10.1016/S0040-4020(03)01147-5

DO - 10.1016/S0040-4020(03)01147-5

M3 - Article

SN - 0040-4020

VL - 59

SP - 7385

EP - 7388

JO - Tetrahedron

JF - Tetrahedron

IS - 59

ER -

3-benzoyl-1,2,4,5-tetraphenylpentane-1.5-dione. A molecular paddlewheel

Abstract

Keywords

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