A Cyclic Hexacopper (II) fluoro Complex that Encapsulates Two Flouride Anions

Abbie McLaughlin, X. Liu, M. P. De Miranda, A. J. L. McInnes, C. A. Kilner, M. A. Halcrow

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

The complex [{Cu-3(Hpz(tBu))(4)(mu-pz(tBu))(2)(mu-F)(2)(mu(3)-F)}(2)]F-2 (Hpz(tBu) = 3{5}-tert-butylpyrazole) has a cyclic, C-2v-symmetric hexacopper core. The two non-coordinated F- anions are encapsulated within cavities formed by three Hpz(tBu) ligands.

Original languageEnglish
Pages (from-to)2978-2979
Number of pages1
JournalChemical Communications
DOIs
Publication statusPublished - 2002

Keywords

  • MAGNETIC-PROPERTIES
  • LIGANDS
  • CRYSTAL
  • DIMERS

Cite this

McLaughlin, A., Liu, X., De Miranda, M. P., McInnes, A. J. L., Kilner, C. A., & Halcrow, M. A. (2002). A Cyclic Hexacopper (II) fluoro Complex that Encapsulates Two Flouride Anions. Chemical Communications, 2978-2979. https://doi.org/10.1039/b207923m

A Cyclic Hexacopper (II) fluoro Complex that Encapsulates Two Flouride Anions. / McLaughlin, Abbie; Liu, X.; De Miranda, M. P.; McInnes, A. J. L.; Kilner, C. A.; Halcrow, M. A.

In: Chemical Communications, 2002, p. 2978-2979.

Research output: Contribution to journalArticle

McLaughlin, Abbie ; Liu, X. ; De Miranda, M. P. ; McInnes, A. J. L. ; Kilner, C. A. ; Halcrow, M. A. / A Cyclic Hexacopper (II) fluoro Complex that Encapsulates Two Flouride Anions. In: Chemical Communications. 2002 ; pp. 2978-2979.
@article{ad84ef5a79a14eb59e0bb72f80cfef0e,
title = "A Cyclic Hexacopper (II) fluoro Complex that Encapsulates Two Flouride Anions",
abstract = "The complex [{Cu-3(Hpz(tBu))(4)(mu-pz(tBu))(2)(mu-F)(2)(mu(3)-F)}(2)]F-2 (Hpz(tBu) = 3{5}-tert-butylpyrazole) has a cyclic, C-2v-symmetric hexacopper core. The two non-coordinated F- anions are encapsulated within cavities formed by three Hpz(tBu) ligands.",
keywords = "MAGNETIC-PROPERTIES, LIGANDS, CRYSTAL, DIMERS",
author = "Abbie McLaughlin and X. Liu and {De Miranda}, {M. P.} and McInnes, {A. J. L.} and Kilner, {C. A.} and Halcrow, {M. A.}",
year = "2002",
doi = "10.1039/b207923m",
language = "English",
pages = "2978--2979",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - A Cyclic Hexacopper (II) fluoro Complex that Encapsulates Two Flouride Anions

AU - McLaughlin, Abbie

AU - Liu, X.

AU - De Miranda, M. P.

AU - McInnes, A. J. L.

AU - Kilner, C. A.

AU - Halcrow, M. A.

PY - 2002

Y1 - 2002

N2 - The complex [{Cu-3(Hpz(tBu))(4)(mu-pz(tBu))(2)(mu-F)(2)(mu(3)-F)}(2)]F-2 (Hpz(tBu) = 3{5}-tert-butylpyrazole) has a cyclic, C-2v-symmetric hexacopper core. The two non-coordinated F- anions are encapsulated within cavities formed by three Hpz(tBu) ligands.

AB - The complex [{Cu-3(Hpz(tBu))(4)(mu-pz(tBu))(2)(mu-F)(2)(mu(3)-F)}(2)]F-2 (Hpz(tBu) = 3{5}-tert-butylpyrazole) has a cyclic, C-2v-symmetric hexacopper core. The two non-coordinated F- anions are encapsulated within cavities formed by three Hpz(tBu) ligands.

KW - MAGNETIC-PROPERTIES

KW - LIGANDS

KW - CRYSTAL

KW - DIMERS

U2 - 10.1039/b207923m

DO - 10.1039/b207923m

M3 - Article

SP - 2978

EP - 2979

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

ER -