A Cyclic Hexacopper (II) fluoro Complex that Encapsulates Two Flouride Anions

Abbie McLaughlin, X. Liu, M. P. De Miranda, A. J. L. McInnes, C. A. Kilner, M. A. Halcrow

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

The complex [{Cu-3(Hpz(tBu))(4)(mu-pz(tBu))(2)(mu-F)(2)(mu(3)-F)}(2)]F-2 (Hpz(tBu) = 3{5}-tert-butylpyrazole) has a cyclic, C-2v-symmetric hexacopper core. The two non-coordinated F- anions are encapsulated within cavities formed by three Hpz(tBu) ligands.

Original languageEnglish
Pages (from-to)2978-2979
Number of pages1
JournalChemical Communications
DOIs
Publication statusPublished - 2002

Keywords

  • MAGNETIC-PROPERTIES
  • LIGANDS
  • CRYSTAL
  • DIMERS

Cite this

McLaughlin, A., Liu, X., De Miranda, M. P., McInnes, A. J. L., Kilner, C. A., & Halcrow, M. A. (2002). A Cyclic Hexacopper (II) fluoro Complex that Encapsulates Two Flouride Anions. Chemical Communications, 2978-2979. https://doi.org/10.1039/b207923m