A Fourier transform mass spectrometry study of ethene oligomers in HMFI zeolite

S J  Jeong; K J  Fisher; Russell Francis Howe; G D  Willett

doi:10.1016/S1387-1811(98)00130-9

A Fourier transform mass spectrometry study of ethene oligomers in HMFI zeolite

S J Jeong, K J Fisher, Russell Francis Howe, G D Willett

Chemistry

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7 Citations (Scopus)

Abstract

Fourier transform ion cyclotron resonance mass spectrometry is applied to identify adsorbed species formed from ethene in zeolite HMFI. Long chain alkenes (up to 18 carbon atoms) are detected from the zeolite exposed to ethene at 298 K from vacuum desorption, laser induced desorption and laser ablation-chemical ionization experiments. Reaction with ethene at 420 K forms a mixture of linear alkenes, branched alkanes, and some mononuclear aromatics. After reaction at 560 K, the major adsorbed species are alkylbenzenes and alkylnaphthalenes. (C) 1998 Elsevier Science B.V. All rights reserved.

Original language	English
Pages (from-to)	369-377
Number of pages	9
Journal	Microporous and Mesoporous Materials
Volume	22
Issue number	1-3
DOIs	https://doi.org/10.1016/S1387-1811(98)00130-9
Publication status	Published - 17 Jun 1998

Keywords

zeolite
Fourier transform ion cyclotron resonance mass spectrometry
ethene oligomerization
ethene polymerization
laser ablation
desorption
H-ZSM-5
propene

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10.1016/S1387-1811(98)00130-9

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title = "A Fourier transform mass spectrometry study of ethene oligomers in HMFI zeolite",

abstract = "Fourier transform ion cyclotron resonance mass spectrometry is applied to identify adsorbed species formed from ethene in zeolite HMFI. Long chain alkenes (up to 18 carbon atoms) are detected from the zeolite exposed to ethene at 298 K from vacuum desorption, laser induced desorption and laser ablation-chemical ionization experiments. Reaction with ethene at 420 K forms a mixture of linear alkenes, branched alkanes, and some mononuclear aromatics. After reaction at 560 K, the major adsorbed species are alkylbenzenes and alkylnaphthalenes. (C) 1998 Elsevier Science B.V. All rights reserved.",

keywords = "zeolite, Fourier transform ion cyclotron resonance mass spectrometry, ethene oligomerization, ethene polymerization, laser ablation, desorption, H-ZSM-5, propene",

author = "Jeong, {S J} and Fisher, {K J} and Howe, {Russell Francis} and Willett, {G D}",

year = "1998",

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doi = "10.1016/S1387-1811(98)00130-9",

language = "English",

volume = "22",

pages = "369--377",

journal = "Microporous and Mesoporous Materials",

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TY - JOUR

T1 - A Fourier transform mass spectrometry study of ethene oligomers in HMFI zeolite

AU - Jeong, S J

AU - Fisher, K J

AU - Howe, Russell Francis

AU - Willett, G D

PY - 1998/6/17

Y1 - 1998/6/17

N2 - Fourier transform ion cyclotron resonance mass spectrometry is applied to identify adsorbed species formed from ethene in zeolite HMFI. Long chain alkenes (up to 18 carbon atoms) are detected from the zeolite exposed to ethene at 298 K from vacuum desorption, laser induced desorption and laser ablation-chemical ionization experiments. Reaction with ethene at 420 K forms a mixture of linear alkenes, branched alkanes, and some mononuclear aromatics. After reaction at 560 K, the major adsorbed species are alkylbenzenes and alkylnaphthalenes. (C) 1998 Elsevier Science B.V. All rights reserved.

AB - Fourier transform ion cyclotron resonance mass spectrometry is applied to identify adsorbed species formed from ethene in zeolite HMFI. Long chain alkenes (up to 18 carbon atoms) are detected from the zeolite exposed to ethene at 298 K from vacuum desorption, laser induced desorption and laser ablation-chemical ionization experiments. Reaction with ethene at 420 K forms a mixture of linear alkenes, branched alkanes, and some mononuclear aromatics. After reaction at 560 K, the major adsorbed species are alkylbenzenes and alkylnaphthalenes. (C) 1998 Elsevier Science B.V. All rights reserved.

KW - zeolite

KW - Fourier transform ion cyclotron resonance mass spectrometry

KW - ethene oligomerization

KW - ethene polymerization

KW - laser ablation

KW - desorption

KW - H-ZSM-5

KW - propene

U2 - 10.1016/S1387-1811(98)00130-9

DO - 10.1016/S1387-1811(98)00130-9

M3 - Article

SN - 1387-1811

VL - 22

SP - 369

EP - 377

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

IS - 1-3

ER -

A Fourier transform mass spectrometry study of ethene oligomers in HMFI zeolite

Abstract

Keywords

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