A Mossbauer study of biotite weathering

Clive Maitland Rice, J.M. Williams

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Summary: Fresh and weathered biotites have been studied using Mössbauer, chemical, and X-ray analytical techniques. In the Mössbauer spectra the complete interference of both low-spin ferric lines by one of the high-spin ferrous lines and the existence of high-spin ferric iron in the weathered biotite has been demonstrated. In view of this interference, which appears to be common, allowances must be made in spectral interpretation if chemical analysis reveals ferric iron to be present in detectable amounts. Hypothetical extension of the weathering trends observed suggests that high-spin ferric iron is the only stable iron species in the end product.

During weathering marked loss of ferrous iron occurs, whereas the ferric iron content remains approximately constant. As a result of the instability of ferrous iron in the weathering environment there is a significant rearrangement of the octahedral layer.
Original languageEnglish
Pages (from-to)210-215
Number of pages6
JournalMineralogical Magazine
Volume37
Issue number286
DOIs
Publication statusPublished - Jun 1969

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Weathering
biotite
weathering
Iron
iron
chemical analysis
analytical method
X rays
Chemical analysis

Cite this

A Mossbauer study of biotite weathering. / Rice, Clive Maitland; Williams, J.M.

In: Mineralogical Magazine, Vol. 37, No. 286, 06.1969, p. 210-215.

Research output: Contribution to journalArticle

Rice, Clive Maitland ; Williams, J.M. / A Mossbauer study of biotite weathering. In: Mineralogical Magazine. 1969 ; Vol. 37, No. 286. pp. 210-215.
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AB - Summary: Fresh and weathered biotites have been studied using Mössbauer, chemical, and X-ray analytical techniques. In the Mössbauer spectra the complete interference of both low-spin ferric lines by one of the high-spin ferrous lines and the existence of high-spin ferric iron in the weathered biotite has been demonstrated. In view of this interference, which appears to be common, allowances must be made in spectral interpretation if chemical analysis reveals ferric iron to be present in detectable amounts. Hypothetical extension of the weathering trends observed suggests that high-spin ferric iron is the only stable iron species in the end product.During weathering marked loss of ferrous iron occurs, whereas the ferric iron content remains approximately constant. As a result of the instability of ferrous iron in the weathering environment there is a significant rearrangement of the octahedral layer.

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