A new one-dimensional coordination polymer of silver(I) with bridging 2-(2-aminoethyl)pyridine and nitrato ligands: [Ag-2(mu-NO3)(2)(mu-aepy)(2)](n)

E Senel, V T Yilmaz, W T A Harrison

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

A new silver(I) nitrate complex of 2-(2-aminoethyl)pyridine (aepy), [Ag-2(mu-NO3)(2)(mu-aepy)(2)](n), has been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffractometry. Two silver(l) ions are doubly bridged by two bidentate aepy ligands forming dimeric building block [Ag-2(mu-aepy)(2)] units with a Ag (...) Ag distance of 3.0587(17) angstrom. These dimeric units are further doubly bridged by two nitrato ligands into a one-dimensional polymeric chain. The nitrato ligand exhibits an uncommon bidentate bridging mode of Ag-ONO-Ag. The title complex features a hydrogen bonded two-dimensional supramolecular framework formed via N-H (...) O hydrogen bonds, involving the uncoordinated O atom of the nitrate ligand and amine hydrogen atoms of aepy. The thermal stability of the title complex was investigated using thermogravimetry and differential thermal analysis.

Original languageEnglish
Pages (from-to)659-662
Number of pages4
JournalZeitschrift für Naturforschung. B, Journal of Chemical Sciences
Volume60
Publication statusPublished - 2005

Keywords

  • 2-(2-aminoethyl)-pyridine
  • nitrato
  • silver(I)
  • one-dimensional coordination polymer
  • crystal structure
  • CRYSTAL-STRUCTURES
  • TRANS-BIS(SACCHARINATO)CADMIUM(II) COMPLEXES
  • STRUCTURAL-CHARACTERIZATION
  • THERMAL CHARACTERIZATION
  • IR-SPECTRA
  • 2-AMINOMETHYLPYRIDINE
  • 2-AMINOETHYLPYRIDINE
  • 2-PYRIDINEPROPANOL
  • NI(II)
  • CU(II)

Cite this

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title = "A new one-dimensional coordination polymer of silver(I) with bridging 2-(2-aminoethyl)pyridine and nitrato ligands: [Ag-2(mu-NO3)(2)(mu-aepy)(2)](n)",
abstract = "A new silver(I) nitrate complex of 2-(2-aminoethyl)pyridine (aepy), [Ag-2(mu-NO3)(2)(mu-aepy)(2)](n), has been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffractometry. Two silver(l) ions are doubly bridged by two bidentate aepy ligands forming dimeric building block [Ag-2(mu-aepy)(2)] units with a Ag (...) Ag distance of 3.0587(17) angstrom. These dimeric units are further doubly bridged by two nitrato ligands into a one-dimensional polymeric chain. The nitrato ligand exhibits an uncommon bidentate bridging mode of Ag-ONO-Ag. The title complex features a hydrogen bonded two-dimensional supramolecular framework formed via N-H (...) O hydrogen bonds, involving the uncoordinated O atom of the nitrate ligand and amine hydrogen atoms of aepy. The thermal stability of the title complex was investigated using thermogravimetry and differential thermal analysis.",
keywords = "2-(2-aminoethyl)-pyridine, nitrato, silver(I), one-dimensional coordination polymer, crystal structure, CRYSTAL-STRUCTURES, TRANS-BIS(SACCHARINATO)CADMIUM(II) COMPLEXES, STRUCTURAL-CHARACTERIZATION, THERMAL CHARACTERIZATION, IR-SPECTRA, 2-AMINOMETHYLPYRIDINE, 2-AMINOETHYLPYRIDINE, 2-PYRIDINEPROPANOL, NI(II), CU(II)",
author = "E Senel and Yilmaz, {V T} and Harrison, {W T A}",
year = "2005",
language = "English",
volume = "60",
pages = "659--662",
journal = "Zeitschrift f{\"u}r Naturforschung. B, Journal of Chemical Sciences",
issn = "0932-0776",
publisher = "Verlag der Zeitschrift fur Naturforschung",

}

TY - JOUR

T1 - A new one-dimensional coordination polymer of silver(I) with bridging 2-(2-aminoethyl)pyridine and nitrato ligands: [Ag-2(mu-NO3)(2)(mu-aepy)(2)](n)

AU - Senel, E

AU - Yilmaz, V T

AU - Harrison, W T A

PY - 2005

Y1 - 2005

N2 - A new silver(I) nitrate complex of 2-(2-aminoethyl)pyridine (aepy), [Ag-2(mu-NO3)(2)(mu-aepy)(2)](n), has been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffractometry. Two silver(l) ions are doubly bridged by two bidentate aepy ligands forming dimeric building block [Ag-2(mu-aepy)(2)] units with a Ag (...) Ag distance of 3.0587(17) angstrom. These dimeric units are further doubly bridged by two nitrato ligands into a one-dimensional polymeric chain. The nitrato ligand exhibits an uncommon bidentate bridging mode of Ag-ONO-Ag. The title complex features a hydrogen bonded two-dimensional supramolecular framework formed via N-H (...) O hydrogen bonds, involving the uncoordinated O atom of the nitrate ligand and amine hydrogen atoms of aepy. The thermal stability of the title complex was investigated using thermogravimetry and differential thermal analysis.

AB - A new silver(I) nitrate complex of 2-(2-aminoethyl)pyridine (aepy), [Ag-2(mu-NO3)(2)(mu-aepy)(2)](n), has been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffractometry. Two silver(l) ions are doubly bridged by two bidentate aepy ligands forming dimeric building block [Ag-2(mu-aepy)(2)] units with a Ag (...) Ag distance of 3.0587(17) angstrom. These dimeric units are further doubly bridged by two nitrato ligands into a one-dimensional polymeric chain. The nitrato ligand exhibits an uncommon bidentate bridging mode of Ag-ONO-Ag. The title complex features a hydrogen bonded two-dimensional supramolecular framework formed via N-H (...) O hydrogen bonds, involving the uncoordinated O atom of the nitrate ligand and amine hydrogen atoms of aepy. The thermal stability of the title complex was investigated using thermogravimetry and differential thermal analysis.

KW - 2-(2-aminoethyl)-pyridine

KW - nitrato

KW - silver(I)

KW - one-dimensional coordination polymer

KW - crystal structure

KW - CRYSTAL-STRUCTURES

KW - TRANS-BIS(SACCHARINATO)CADMIUM(II) COMPLEXES

KW - STRUCTURAL-CHARACTERIZATION

KW - THERMAL CHARACTERIZATION

KW - IR-SPECTRA

KW - 2-AMINOMETHYLPYRIDINE

KW - 2-AMINOETHYLPYRIDINE

KW - 2-PYRIDINEPROPANOL

KW - NI(II)

KW - CU(II)

M3 - Article

VL - 60

SP - 659

EP - 662

JO - Zeitschrift für Naturforschung. B, Journal of Chemical Sciences

JF - Zeitschrift für Naturforschung. B, Journal of Chemical Sciences

SN - 0932-0776

ER -