A new synthetic route to donor -acceptor Porphyrins

Michael John Plater; S. Aiken; G. Bourhill

doi:10.1016/S0040-4020(02)00109-6

A new synthetic route to donor -acceptor Porphyrins

Michael John Plater, S. Aiken, G. Bourhill

Chemistry

Research output: Contribution to journal › Article › peer-review

88 Citations (Scopus)

Abstract

Some new donor-acceptor porphyrins have been prepared based on a metallated bis(ethynyl) porphyrin core. 4-(Dimethylamino)phenyl was used as the donor group and 4-nitrophenyl, 4-cyanophenyl and 5-nitrothiazoyl as the acceptor groups. Dipyrrylmethane was used for large scale porphyrin ring synthesis because the absence of methylene substituents reduces the difficulty of substituent scrambling that occurs during parphyrin synthesis. (C) 2002 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	2405-2413
Number of pages	8
Journal	Tetrahedron
Volume	58
DOIs	https://doi.org/10.1016/S0040-4020(02)00109-6
Publication status	Published - 2002

Keywords

porphyrins and analogues
palladium and compounds
ELECTRONIC-STRUCTURE
CRYSTAL
PHTHALOCYANINE
POLYMER
SYSTEMS

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10.1016/S0040-4020(02)00109-6

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title = "A new synthetic route to donor -acceptor Porphyrins",

abstract = "Some new donor-acceptor porphyrins have been prepared based on a metallated bis(ethynyl) porphyrin core. 4-(Dimethylamino)phenyl was used as the donor group and 4-nitrophenyl, 4-cyanophenyl and 5-nitrothiazoyl as the acceptor groups. Dipyrrylmethane was used for large scale porphyrin ring synthesis because the absence of methylene substituents reduces the difficulty of substituent scrambling that occurs during parphyrin synthesis. (C) 2002 Elsevier Science Ltd. All rights reserved.",

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doi = "10.1016/S0040-4020(02)00109-6",

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TY - JOUR

T1 - A new synthetic route to donor -acceptor Porphyrins

AU - Plater, Michael John

AU - Aiken, S.

AU - Bourhill, G.

PY - 2002

Y1 - 2002

N2 - Some new donor-acceptor porphyrins have been prepared based on a metallated bis(ethynyl) porphyrin core. 4-(Dimethylamino)phenyl was used as the donor group and 4-nitrophenyl, 4-cyanophenyl and 5-nitrothiazoyl as the acceptor groups. Dipyrrylmethane was used for large scale porphyrin ring synthesis because the absence of methylene substituents reduces the difficulty of substituent scrambling that occurs during parphyrin synthesis. (C) 2002 Elsevier Science Ltd. All rights reserved.

AB - Some new donor-acceptor porphyrins have been prepared based on a metallated bis(ethynyl) porphyrin core. 4-(Dimethylamino)phenyl was used as the donor group and 4-nitrophenyl, 4-cyanophenyl and 5-nitrothiazoyl as the acceptor groups. Dipyrrylmethane was used for large scale porphyrin ring synthesis because the absence of methylene substituents reduces the difficulty of substituent scrambling that occurs during parphyrin synthesis. (C) 2002 Elsevier Science Ltd. All rights reserved.

KW - porphyrins and analogues

KW - palladium and compounds

KW - ELECTRONIC-STRUCTURE

KW - CRYSTAL

KW - PHTHALOCYANINE

KW - POLYMER

KW - SYSTEMS

U2 - 10.1016/S0040-4020(02)00109-6

DO - 10.1016/S0040-4020(02)00109-6

M3 - Article

VL - 58

SP - 2405

EP - 2413

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

ER -

A new synthetic route to donor -acceptor Porphyrins

Abstract

Keywords

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