A one-dimensional lead(II) coordination polymer with bridging saccharinate and 2-aminomethylpyridine ligands: Synthesis, IR spectra, and crystal structure of [Pb(ampy)(mu-sac)(2)](n)

V T Yilmaz, S Caglar, W T A Harrison

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

A complex with eight-coordinate lead(n) atom and saccharinate (sac) and 2-aminomethylpyridine ligands was characterized by IR, elemental analysis and X-ray crystallography. The lead(II) complex crystallizes in the monoclinic crystal system with space group P2(1)/c. The single crystal X-ray analysis shows that the complex is a coordination polymer, [Pb(ampy)(mu-sac)(2)](n), in which the lead(II) ions have a highly distorted bicapped trigonal antiprism coordination. Lead(II) ions are bridged by carboxyl groups of sac forming one-dimensional linear chains, running parallel to the a axis. The intrachain Pb... Ph distances are 4.4490(3) and 4.4679(3) Angstrom. The individual chains are connected by N-H...O-sulfonyl and C-ampy-H...O-sulfonyl type hydrogen bonds, resulting in a three-dimensional network. The sac ligand acts as bidentate and bridging ligand, while ampy behaves as an N,N' donor. The IR spectra of the lead(II) complex are discussed in detail.

Original languageEnglish
Pages (from-to)948-951
Number of pages4
JournalZeitschrift für Anorganische und Allgemeine Chemie
Volume630
DOIs
Publication statusPublished - 2004

Keywords

  • lead
  • 2-aminomethylpyridine
  • saccharinate
  • polymeric structure
  • crystal structure
  • DISACCHARINATE
  • COMPLEXES
  • <M(C7H4NO3S)2(H2O)4>.2H2O
  • MONOHYDRATE

Cite this