Abstract
Treatment of N-phenyl-p-phenylenediamine and two equivalents of aniline with potassium dichromate in hot water acidified with a small amount of sulfuric acid gives 3-phenylamino-5-phenyl-7-aminophenazinium sulfate (pseudomauveine). The oxidation of N-phenyl-p-phenylenediamine and o-toluidine with potassium dichromate in water with a small amount of sulfuric acid gives 3-phenylamino-5-(o-toluyl)-7-amino-8-methylphenazinium sulfate. Oxidation of aniline and (o or p) toluidine only gave small quantities of mauveine chromophores. Oxidation of p-toluidine gives a known dimer which gives a purple coloured solution in acid. A hypothesis is described in which N-phenyl-p-phenylenediamine may have been involved in mauveine synthesis in the nineteenth century.
Original language | English |
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Pages (from-to) | 304-309 |
Number of pages | 6 |
Journal | Journal of Chemical Research |
Volume | 35 |
Issue number | 5 |
DOIs | |
Publication status | Published - May 2011 |
Keywords
- aniline purple
- coal tar dyes
- mauve
- mauveine
- pseudo-mauviene