A three-dimensional hydrogen-bonded framework in N-(3-nitrophenyl)phthalimide, and hydrogen-bonded chains of rings in N-(3,5-dinitrophenyl)phthalimide, linked into sheets by dipolar interactions

C Glidewell, J N Low, J M S Skakle, J L Wardell

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Abstract

Molecules of N-(3-nitrophenyl) phthalimide, C14H8N2O4, are linked into a three-dimensional framework by four distinct C-H...O hydrogen bonds [H...O=2.35-2.58 Angstrom, C...O=3.105 (5)-3.432 (5) Angstrom and C-H...O=128-167degrees]. Molecules of N-(3,5-dinitrophenyl) phthalimide, C14H7N3O6, lie across twofold rotation axes in space group P2/n and are linked by a single C-H...O hydrogen bond [H...O=2.58 Angstrom, C...O=3.410 (2) Angstrom and C-H...O=147degrees] into chains of rings. These chains are weakly linked into sheets by intermolecular interactions involving short dipolar O...N and O...C contacts.

Original languageEnglish
Number of pages4
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume60
DOIs
Publication statusPublished - 2004

Keywords

  • CRYSTAL

Cite this

@article{83ba82d8b4ae4c4fa88554e88cd7b6b0,
title = "A three-dimensional hydrogen-bonded framework in N-(3-nitrophenyl)phthalimide, and hydrogen-bonded chains of rings in N-(3,5-dinitrophenyl)phthalimide, linked into sheets by dipolar interactions",
abstract = "Molecules of N-(3-nitrophenyl) phthalimide, C14H8N2O4, are linked into a three-dimensional framework by four distinct C-H...O hydrogen bonds [H...O=2.35-2.58 Angstrom, C...O=3.105 (5)-3.432 (5) Angstrom and C-H...O=128-167degrees]. Molecules of N-(3,5-dinitrophenyl) phthalimide, C14H7N3O6, lie across twofold rotation axes in space group P2/n and are linked by a single C-H...O hydrogen bond [H...O=2.58 Angstrom, C...O=3.410 (2) Angstrom and C-H...O=147degrees] into chains of rings. These chains are weakly linked into sheets by intermolecular interactions involving short dipolar O...N and O...C contacts.",
keywords = "CRYSTAL",
author = "C Glidewell and Low, {J N} and Skakle, {J M S} and Wardell, {J L}",
year = "2004",
doi = "10.1107/S0108270103026052",
language = "English",
volume = "60",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",

}

TY - JOUR

T1 - A three-dimensional hydrogen-bonded framework in N-(3-nitrophenyl)phthalimide, and hydrogen-bonded chains of rings in N-(3,5-dinitrophenyl)phthalimide, linked into sheets by dipolar interactions

AU - Glidewell, C

AU - Low, J N

AU - Skakle, J M S

AU - Wardell, J L

PY - 2004

Y1 - 2004

N2 - Molecules of N-(3-nitrophenyl) phthalimide, C14H8N2O4, are linked into a three-dimensional framework by four distinct C-H...O hydrogen bonds [H...O=2.35-2.58 Angstrom, C...O=3.105 (5)-3.432 (5) Angstrom and C-H...O=128-167degrees]. Molecules of N-(3,5-dinitrophenyl) phthalimide, C14H7N3O6, lie across twofold rotation axes in space group P2/n and are linked by a single C-H...O hydrogen bond [H...O=2.58 Angstrom, C...O=3.410 (2) Angstrom and C-H...O=147degrees] into chains of rings. These chains are weakly linked into sheets by intermolecular interactions involving short dipolar O...N and O...C contacts.

AB - Molecules of N-(3-nitrophenyl) phthalimide, C14H8N2O4, are linked into a three-dimensional framework by four distinct C-H...O hydrogen bonds [H...O=2.35-2.58 Angstrom, C...O=3.105 (5)-3.432 (5) Angstrom and C-H...O=128-167degrees]. Molecules of N-(3,5-dinitrophenyl) phthalimide, C14H7N3O6, lie across twofold rotation axes in space group P2/n and are linked by a single C-H...O hydrogen bond [H...O=2.58 Angstrom, C...O=3.410 (2) Angstrom and C-H...O=147degrees] into chains of rings. These chains are weakly linked into sheets by intermolecular interactions involving short dipolar O...N and O...C contacts.

KW - CRYSTAL

U2 - 10.1107/S0108270103026052

DO - 10.1107/S0108270103026052

M3 - Article

VL - 60

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -