AM-6: a microporous one-dimensional ferromagnet

Rachel M. Yeates; Morag J. Murdoch; Peter D. Southon; Abbie McLaughlin; Russell Francis Howe; Francesca Bonino; Silvia Bordiga; Alessandro Damin

doi:10.1039/b908099f

AM-6: a microporous one-dimensional ferromagnet

Rachel M. Yeates, Morag J. Murdoch, Peter D. Southon, Abbie McLaughlin, Russell Francis Howe, Francesca Bonino, Silvia Bordiga, Alessandro Damin

Chemistry

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The vanadosilicate zeolite AM-6 is shown by a combination of spectroscopic techniques (UV-vis, Raman, XPS, XAS and EPR) to contain linear chains of alternating V=O and V-O bonds. The V(IV) ions in these chains are ferromagnetically coupled, and an excellent fit a to the susceptibility data with a one-dimensional Heisenberg model is obtained with J = 0.66(1) cm(-1). AM-6 is thus the first reported example of a microporous material incorporating one-dimensional ferromagnetic chains.

Original language	English
Pages (from-to)	8025-8032
Number of pages	8
Journal	Dalton Transactions
Issue number	38
DOIs	https://doi.org/10.1039/b908099f
Publication status	Published - 2009

Keywords

titanosilicate ETS-10
open-framework
magnetic-properties
hydrothermal synthesis
vanadium silicates
molecular-sieve
quantum wires
behavior
spectroscopy
adsoption

Access to Document

10.1039/b908099f

Cite this

@article{4178f4ee6a364f94a45e08753cb5ed37,

title = "AM-6: a microporous one-dimensional ferromagnet",

abstract = "The vanadosilicate zeolite AM-6 is shown by a combination of spectroscopic techniques (UV-vis, Raman, XPS, XAS and EPR) to contain linear chains of alternating V=O and V-O bonds. The V(IV) ions in these chains are ferromagnetically coupled, and an excellent fit a to the susceptibility data with a one-dimensional Heisenberg model is obtained with J = 0.66(1) cm(-1). AM-6 is thus the first reported example of a microporous material incorporating one-dimensional ferromagnetic chains.",

keywords = "titanosilicate ETS-10, open-framework, magnetic-properties, hydrothermal synthesis, vanadium silicates, molecular-sieve, quantum wires, behavior, spectroscopy, adsoption",

author = "Yeates, {Rachel M.} and Murdoch, {Morag J.} and Southon, {Peter D.} and Abbie McLaughlin and Howe, {Russell Francis} and Francesca Bonino and Silvia Bordiga and Alessandro Damin",

year = "2009",

doi = "10.1039/b908099f",

language = "English",

pages = "8025--8032",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "38",

}

TY - JOUR

T1 - AM-6: a microporous one-dimensional ferromagnet

AU - Yeates, Rachel M.

AU - Murdoch, Morag J.

AU - Southon, Peter D.

AU - McLaughlin, Abbie

AU - Howe, Russell Francis

AU - Bonino, Francesca

AU - Bordiga, Silvia

AU - Damin, Alessandro

PY - 2009

Y1 - 2009

N2 - The vanadosilicate zeolite AM-6 is shown by a combination of spectroscopic techniques (UV-vis, Raman, XPS, XAS and EPR) to contain linear chains of alternating V=O and V-O bonds. The V(IV) ions in these chains are ferromagnetically coupled, and an excellent fit a to the susceptibility data with a one-dimensional Heisenberg model is obtained with J = 0.66(1) cm(-1). AM-6 is thus the first reported example of a microporous material incorporating one-dimensional ferromagnetic chains.

AB - The vanadosilicate zeolite AM-6 is shown by a combination of spectroscopic techniques (UV-vis, Raman, XPS, XAS and EPR) to contain linear chains of alternating V=O and V-O bonds. The V(IV) ions in these chains are ferromagnetically coupled, and an excellent fit a to the susceptibility data with a one-dimensional Heisenberg model is obtained with J = 0.66(1) cm(-1). AM-6 is thus the first reported example of a microporous material incorporating one-dimensional ferromagnetic chains.

KW - titanosilicate ETS-10

KW - open-framework

KW - magnetic-properties

KW - hydrothermal synthesis

KW - vanadium silicates

KW - molecular-sieve

KW - quantum wires

KW - behavior

KW - spectroscopy

KW - adsoption

U2 - 10.1039/b908099f

DO - 10.1039/b908099f

M3 - Article

SN - 1477-9226

SP - 8025

EP - 8032

JO - Dalton Transactions

JF - Dalton Transactions

IS - 38

ER -

AM-6: a microporous one-dimensional ferromagnet

Abstract

Keywords

Access to Document

Fingerprint

Cite this