TY - JOUR
T1 - Amino Acid Templating of Inorganic Networks
T2 - Synthesis and Structure of L-Asparagine Zinc Phosphite, C4N2O3H 8·ZnHPO3
AU - Gordon, Laura E.
AU - Harrison, William T.A.
PY - 2004/3/22
Y1 - 2004/3/22
N2 - C4N2O3H8·ZnHPO 3 is the first zincophosphite framework to be templated by an amino acid (L-asparagine), which bonds to Zn via a carboxyl O atom. It contains infinite, homochiral, helical 4-ring chains of ZnO4 and HPO 3 groups, stabilized by intra- and interchain N-H⋯O hydrogen bonds. Crystal data: C4N2O3H 8·ZnHPO3, Mr = 277.49, orthorhombic, P212121 (No. 19), a = 5.0349(2) Å, b = 9.4539(4) Å, c = 18.6092(8) Å, V = 885,79 (6) Å3, Z = 4.
AB - C4N2O3H8·ZnHPO 3 is the first zincophosphite framework to be templated by an amino acid (L-asparagine), which bonds to Zn via a carboxyl O atom. It contains infinite, homochiral, helical 4-ring chains of ZnO4 and HPO 3 groups, stabilized by intra- and interchain N-H⋯O hydrogen bonds. Crystal data: C4N2O3H 8·ZnHPO3, Mr = 277.49, orthorhombic, P212121 (No. 19), a = 5.0349(2) Å, b = 9.4539(4) Å, c = 18.6092(8) Å, V = 885,79 (6) Å3, Z = 4.
UR - http://www.scopus.com/inward/record.url?scp=1642305005&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:1642305005
SN - 0020-1669
VL - 43
SP - 1808
EP - 1809
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 6
ER -