An extreme case of ZnO6 octahedral distortion in trizinc tris(selenite) hydrate, Zn-3(SeO3)(3)center dot H2O

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Abstract

Triziac tris[trioxoselenate(IV)] hydrate, Zn-3(SeO3)(3). H2O is built up from ZnO6 octahedra [d(av)(Zn-O) = 2.127 (2) Angstrom] and SeO3 pyramids [d(av)(Se-O) = 1.693 (2) Angstrom], sharing vertices and edges. One of the zinc octahedra is exceptionally distorted. The title compound is isostructural with CO3(SeO3)(3). H2O and Ni-3(SeO3)(3). H2O.

Original languageEnglish
Pages (from-to)1980-1983
Number of pages4
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume55
Publication statusPublished - 1999

Keywords

  • CRYSTAL-STRUCTURES
  • NI3(SEO3)3.H2O
  • CO
  • NI

Cite this

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title = "An extreme case of ZnO6 octahedral distortion in trizinc tris(selenite) hydrate, Zn-3(SeO3)(3)center dot H2O",
abstract = "Triziac tris[trioxoselenate(IV)] hydrate, Zn-3(SeO3)(3). H2O is built up from ZnO6 octahedra [d(av)(Zn-O) = 2.127 (2) Angstrom] and SeO3 pyramids [d(av)(Se-O) = 1.693 (2) Angstrom], sharing vertices and edges. One of the zinc octahedra is exceptionally distorted. The title compound is isostructural with CO3(SeO3)(3). H2O and Ni-3(SeO3)(3). H2O.",
keywords = "CRYSTAL-STRUCTURES, NI3(SEO3)3.H2O, CO, NI",
author = "Harrison, {W T A}",
year = "1999",
language = "English",
volume = "55",
pages = "1980--1983",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",

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TY - JOUR

T1 - An extreme case of ZnO6 octahedral distortion in trizinc tris(selenite) hydrate, Zn-3(SeO3)(3)center dot H2O

AU - Harrison, W T A

PY - 1999

Y1 - 1999

N2 - Triziac tris[trioxoselenate(IV)] hydrate, Zn-3(SeO3)(3). H2O is built up from ZnO6 octahedra [d(av)(Zn-O) = 2.127 (2) Angstrom] and SeO3 pyramids [d(av)(Se-O) = 1.693 (2) Angstrom], sharing vertices and edges. One of the zinc octahedra is exceptionally distorted. The title compound is isostructural with CO3(SeO3)(3). H2O and Ni-3(SeO3)(3). H2O.

AB - Triziac tris[trioxoselenate(IV)] hydrate, Zn-3(SeO3)(3). H2O is built up from ZnO6 octahedra [d(av)(Zn-O) = 2.127 (2) Angstrom] and SeO3 pyramids [d(av)(Se-O) = 1.693 (2) Angstrom], sharing vertices and edges. One of the zinc octahedra is exceptionally distorted. The title compound is isostructural with CO3(SeO3)(3). H2O and Ni-3(SeO3)(3). H2O.

KW - CRYSTAL-STRUCTURES

KW - NI3(SEO3)3.H2O

KW - CO

KW - NI

M3 - Article

VL - 55

SP - 1980

EP - 1983

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -