An investigation of the electronic, structural and magnetic properties of the ruddlesden-popper phase Sr3RuCoO7

H. A. Hopper; E. J. Wildman; D. E. Macphee; F. Sher; C. Ritter; M. Lledos; G. Stenning; A. C. McLaughlin

doi:10.1016/j.jssc.2017.06.010

An investigation of the electronic, structural and magnetic properties of the ruddlesden-popper phase Sr₃RuCoO₇

H. A. Hopper, E. J. Wildman, D. E. Macphee, F. Sher, C. Ritter, M. Lledos, G. Stenning, A. C. McLaughlin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

7 Downloads (Pure)

Abstract

The structural, magnetic and electronic properties of the Ruddlesden-Popper material Sr₃CoRuO₇ have been investigated. Examination of the dc and ac magnetic susceptibility demonstrates that Sr₃CoRuO₇ exhibits a spin glass transition at 40 K and a magnetic transition at 140 K. Variable-temperature neutron powder diffraction experiments showed no evidence of magnetic diffraction peaks down to 5 K. This suggests the transition at 140 K is a result of short range magnetic order or magnetic clustering of the Co/Ru spins. Sr₃CoRuO₇ is semiconducting and Mott variable range hopping behaviour is observed below 240 K.

Original language	English
Pages (from-to)	313-317
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	253
Early online date	15 Jun 2017
DOIs	https://doi.org/10.1016/j.jssc.2017.06.010
Publication status	Published - Sep 2017

Keywords

Antiferromagnet
Crystal structure
Diffraction
Neutron
Ruddlesden Popper
Spin glass

Access to Document

10.1016/j.jssc.2017.06.010Licence: Unspecified

Accepted Manuscript
© 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
Accepted author manuscript, 1.06 MBLicence: CC BY-NC-ND

Cite this

@article{f8878bc3de634eeab8e3c902bd8530e5,

title = "An investigation of the electronic, structural and magnetic properties of the ruddlesden-popper phase Sr3RuCoO7",

abstract = "The structural, magnetic and electronic properties of the Ruddlesden-Popper material Sr3CoRuO7 have been investigated. Examination of the dc and ac magnetic susceptibility demonstrates that Sr3CoRuO7 exhibits a spin glass transition at 40 K and a magnetic transition at 140 K. Variable-temperature neutron powder diffraction experiments showed no evidence of magnetic diffraction peaks down to 5 K. This suggests the transition at 140 K is a result of short range magnetic order or magnetic clustering of the Co/Ru spins. Sr3CoRuO7 is semiconducting and Mott variable range hopping behaviour is observed below 240 K.",

keywords = "Antiferromagnet, Crystal structure, Diffraction, Neutron, Ruddlesden Popper, Spin glass",

author = "Hopper, {H. A.} and Wildman, {E. J.} and Macphee, {D. E.} and F. Sher and C. Ritter and M. Lledos and G. Stenning and McLaughlin, {A. C.}",

note = "Acknowledgements We acknowledge the University of Aberdeen for provision of a studentship for Harriet Hopper and the Higher Education Commission of Pakistan for providing a visiting fellowship for Dr. Falak Sher.",

year = "2017",

month = sep,

doi = "10.1016/j.jssc.2017.06.010",

language = "English",

volume = "253",

pages = "313--317",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "ACADEMIC PRESS INC ELSEVIER SCIENCE",

}

TY - JOUR

T1 - An investigation of the electronic, structural and magnetic properties of the ruddlesden-popper phase Sr3RuCoO7

AU - Hopper, H. A.

AU - Wildman, E. J.

AU - Macphee, D. E.

AU - Sher, F.

AU - Ritter, C.

AU - Lledos, M.

AU - Stenning, G.

AU - McLaughlin, A. C.

N1 - Acknowledgements We acknowledge the University of Aberdeen for provision of a studentship for Harriet Hopper and the Higher Education Commission of Pakistan for providing a visiting fellowship for Dr. Falak Sher.

PY - 2017/9

Y1 - 2017/9

N2 - The structural, magnetic and electronic properties of the Ruddlesden-Popper material Sr3CoRuO7 have been investigated. Examination of the dc and ac magnetic susceptibility demonstrates that Sr3CoRuO7 exhibits a spin glass transition at 40 K and a magnetic transition at 140 K. Variable-temperature neutron powder diffraction experiments showed no evidence of magnetic diffraction peaks down to 5 K. This suggests the transition at 140 K is a result of short range magnetic order or magnetic clustering of the Co/Ru spins. Sr3CoRuO7 is semiconducting and Mott variable range hopping behaviour is observed below 240 K.

AB - The structural, magnetic and electronic properties of the Ruddlesden-Popper material Sr3CoRuO7 have been investigated. Examination of the dc and ac magnetic susceptibility demonstrates that Sr3CoRuO7 exhibits a spin glass transition at 40 K and a magnetic transition at 140 K. Variable-temperature neutron powder diffraction experiments showed no evidence of magnetic diffraction peaks down to 5 K. This suggests the transition at 140 K is a result of short range magnetic order or magnetic clustering of the Co/Ru spins. Sr3CoRuO7 is semiconducting and Mott variable range hopping behaviour is observed below 240 K.

KW - Antiferromagnet

KW - Crystal structure

KW - Diffraction

KW - Neutron

KW - Ruddlesden Popper

KW - Spin glass

UR - http://www.scopus.com/inward/record.url?scp=85021168625&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2017.06.010

DO - 10.1016/j.jssc.2017.06.010

M3 - Article

AN - SCOPUS:85021168625

VL - 253

SP - 313

EP - 317

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

ER -

An investigation of the electronic, structural and magnetic properties of the ruddlesden-popper phase Sr₃RuCoO₇

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this