An investigation of the electronic, structural and magnetic properties of the ruddlesden-popper phase Sr3RuCoO7

H. A. Hopper; E. J. Wildman; D. E. Macphee; F. Sher; C. Ritter; M. Lledos; G. Stenning; A. C. McLaughlin

doi:10.1016/j.jssc.2017.06.010

An investigation of the electronic, structural and magnetic properties of the ruddlesden-popper phase Sr₃RuCoO₇

H. A. Hopper, E. J. Wildman, D. E. Macphee, F. Sher, C. Ritter, M. Lledos, G. Stenning, A. C. McLaughlin^*

^*Corresponding author for this work

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Abstract

The structural, magnetic and electronic properties of the Ruddlesden-Popper material Sr₃CoRuO₇ have been investigated. Examination of the dc and ac magnetic susceptibility demonstrates that Sr₃CoRuO₇ exhibits a spin glass transition at 40 K and a magnetic transition at 140 K. Variable-temperature neutron powder diffraction experiments showed no evidence of magnetic diffraction peaks down to 5 K. This suggests the transition at 140 K is a result of short range magnetic order or magnetic clustering of the Co/Ru spins. Sr₃CoRuO₇ is semiconducting and Mott variable range hopping behaviour is observed below 240 K.

Original language	English
Pages (from-to)	313-317
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	253
Early online date	15 Jun 2017
DOIs	https://doi.org/10.1016/j.jssc.2017.06.010
Publication status	Published - Sep 2017

Keywords

Antiferromagnet
Crystal structure
Diffraction
Neutron
Ruddlesden Popper
Spin glass

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title = "An investigation of the electronic, structural and magnetic properties of the ruddlesden-popper phase Sr3RuCoO7",

abstract = "The structural, magnetic and electronic properties of the Ruddlesden-Popper material Sr3CoRuO7 have been investigated. Examination of the dc and ac magnetic susceptibility demonstrates that Sr3CoRuO7 exhibits a spin glass transition at 40 K and a magnetic transition at 140 K. Variable-temperature neutron powder diffraction experiments showed no evidence of magnetic diffraction peaks down to 5 K. This suggests the transition at 140 K is a result of short range magnetic order or magnetic clustering of the Co/Ru spins. Sr3CoRuO7 is semiconducting and Mott variable range hopping behaviour is observed below 240 K.",

keywords = "Antiferromagnet, Crystal structure, Diffraction, Neutron, Ruddlesden Popper, Spin glass",

author = "Hopper, {H. A.} and Wildman, {E. J.} and Macphee, {D. E.} and F. Sher and C. Ritter and M. Lledos and G. Stenning and McLaughlin, {A. C.}",

note = "Acknowledgements We acknowledge the University of Aberdeen for provision of a studentship for Harriet Hopper and the Higher Education Commission of Pakistan for providing a visiting fellowship for Dr. Falak Sher.",

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doi = "10.1016/j.jssc.2017.06.010",

language = "English",

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journal = "Journal of Solid State Chemistry",

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T1 - An investigation of the electronic, structural and magnetic properties of the ruddlesden-popper phase Sr3RuCoO7

AU - Hopper, H. A.

AU - Wildman, E. J.

AU - Macphee, D. E.

AU - Sher, F.

AU - Ritter, C.

AU - Lledos, M.

AU - Stenning, G.

AU - McLaughlin, A. C.

N1 - Acknowledgements We acknowledge the University of Aberdeen for provision of a studentship for Harriet Hopper and the Higher Education Commission of Pakistan for providing a visiting fellowship for Dr. Falak Sher.

PY - 2017/9

Y1 - 2017/9

N2 - The structural, magnetic and electronic properties of the Ruddlesden-Popper material Sr3CoRuO7 have been investigated. Examination of the dc and ac magnetic susceptibility demonstrates that Sr3CoRuO7 exhibits a spin glass transition at 40 K and a magnetic transition at 140 K. Variable-temperature neutron powder diffraction experiments showed no evidence of magnetic diffraction peaks down to 5 K. This suggests the transition at 140 K is a result of short range magnetic order or magnetic clustering of the Co/Ru spins. Sr3CoRuO7 is semiconducting and Mott variable range hopping behaviour is observed below 240 K.

AB - The structural, magnetic and electronic properties of the Ruddlesden-Popper material Sr3CoRuO7 have been investigated. Examination of the dc and ac magnetic susceptibility demonstrates that Sr3CoRuO7 exhibits a spin glass transition at 40 K and a magnetic transition at 140 K. Variable-temperature neutron powder diffraction experiments showed no evidence of magnetic diffraction peaks down to 5 K. This suggests the transition at 140 K is a result of short range magnetic order or magnetic clustering of the Co/Ru spins. Sr3CoRuO7 is semiconducting and Mott variable range hopping behaviour is observed below 240 K.

KW - Antiferromagnet

KW - Crystal structure

KW - Diffraction

KW - Neutron

KW - Ruddlesden Popper

KW - Spin glass

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DO - 10.1016/j.jssc.2017.06.010

M3 - Article

AN - SCOPUS:85021168625

VL - 253

SP - 313

EP - 317

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

ER -

An investigation of the electronic, structural and magnetic properties of the ruddlesden-popper phase Sr₃RuCoO₇

Abstract

Keywords

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