An Organic Zeolite With 10 Å Diameter Pores Assembles From a Soluble and Flexible Building Block by Non‐Covalent Interactions

Michael John Plater; William T A Harrison

doi:10.1002/open.201900006

An Organic Zeolite With 10 Å Diameter Pores Assembles From a Soluble and Flexible Building Block by Non‐Covalent Interactions

Michael John Plater (Corresponding Author), William T A Harrison

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Abstract

Two similar molecular building blocks, which both contain a hydrogen‐bonded nitro group, have been prepared and crystallised. One structure has more flexibility with a butyl side chain which allows an open framework organic zeolite to form with large 10 Å diameter pores, whereas the other structure has less flexibility with an aryl side chain and is close packed. The pore size is comparable with those of the aluminophosphate VPI‐5 (12 Å). It is concluded that some flexibility in the design of the building block for porous organic molecular materials was beneficial.

Original language	English
Pages (from-to)	457-463
Number of pages	7
Journal	ChemistryOpen
Volume	8
Issue number	4
Early online date	8 Apr 2019
DOIs	https://doi.org/10.1002/open.201900006
Publication status	Published - Apr 2019

Keywords

supramolecular chemistry
hydrogen bonds
crystal engineering
organic zeolites

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10.1002/open.201900006Licence: CC BY-NC-ND

An Organic Zeolite With 10 Å Diameter Pores Assembles From a Soluble and Flexible Building Block by Non‐Covalent Interactions
© 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. https://creativecommons.org/licenses/by-nc-nd/4.0/
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Michael Plater

Chemistry (Research Theme)
School of Natural & Computing Sciences, Chemistry - Senior Lecturer

Person: Academic

Cite this

Plater, M. J., & Harrison, W. T. A. (2019). An Organic Zeolite With 10 Å Diameter Pores Assembles From a Soluble and Flexible Building Block by Non‐Covalent Interactions. ChemistryOpen, 8(4), 457-463. https://doi.org/10.1002/open.201900006

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abstract = "Two similar molecular building blocks, which both contain a hydrogen‐bonded nitro group, have been prepared and crystallised. One structure has more flexibility with a butyl side chain which allows an open framework organic zeolite to form with large 10 {\AA} diameter pores, whereas the other structure has less flexibility with an aryl side chain and is close packed. The pore size is comparable with those of the aluminophosphate VPI‐5 (12 {\AA}). It is concluded that some flexibility in the design of the building block for porous organic molecular materials was beneficial.",

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