Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 457-463 |
| Number of pages | 7 |
| Journal | ChemistryOpen |
| Volume | 8 |
| Issue number | 4 |
| Early online date | 8 Apr 2019 |
| DOIs | |
| Publication status | Published - Apr 2019 |
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Keywords
- supramolecular chemistry
- hydrogen bonds
- crystal engineering
- organic zeolites
Cite this
An Organic Zeolite With 10 Å Diameter Pores Assembles From a Soluble and Flexible Building Block by Non‐Covalent Interactions. / Plater, Michael John (Corresponding Author); Harrison, William T A.
In: ChemistryOpen, Vol. 8, No. 4, 04.2019, p. 457-463.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - An Organic Zeolite With 10 Å Diameter Pores Assembles From a Soluble and Flexible Building Block by Non‐Covalent Interactions
AU - Plater, Michael John
AU - Harrison, William T A
N1 - Funding Information Naional Mass Spectrometry Foundation National Crystallography Centre University of Southampton
PY - 2019/4
Y1 - 2019/4
N2 - Two similar molecular building blocks, which both contain a hydrogen‐bonded nitro group, have been prepared and crystallised. One structure has more flexibility with a butyl side chain which allows an open framework organic zeolite to form with large 10 Å diameter pores, whereas the other structure has less flexibility with an aryl side chain and is close packed. The pore size is comparable with those of the aluminophosphate VPI‐5 (12 Å). It is concluded that some flexibility in the design of the building block for porous organic molecular materials was beneficial.
AB - Two similar molecular building blocks, which both contain a hydrogen‐bonded nitro group, have been prepared and crystallised. One structure has more flexibility with a butyl side chain which allows an open framework organic zeolite to form with large 10 Å diameter pores, whereas the other structure has less flexibility with an aryl side chain and is close packed. The pore size is comparable with those of the aluminophosphate VPI‐5 (12 Å). It is concluded that some flexibility in the design of the building block for porous organic molecular materials was beneficial.
KW - supramolecular chemistry
KW - hydrogen bonds
KW - crystal engineering
KW - organic zeolites
UR - http://www.mendeley.com/research/organic-zeolite-10-%C3%A5-diameter-pores-assembles-soluble-flexible-building-block-noncovalent-interactio
U2 - 10.1002/open.201900006
DO - 10.1002/open.201900006
M3 - Article
VL - 8
SP - 457
EP - 463
JO - ChemistryOpen
JF - ChemistryOpen
SN - 2191-1363
IS - 4
ER -