Application of Inelastic Neutron Scattering to the Methanol-to-Gasoline Reaction Over a ZSM-5 Catalyst

Russell F. Howe; James McGregor; Stewart F. Parker; Paul Collier; David Lennon

doi:10.1007/s10562-016-1742-5

Application of Inelastic Neutron Scattering to the Methanol-to-Gasoline Reaction Over a ZSM-5 Catalyst

Russell F. Howe, James McGregor, Stewart F. Parker, Paul Collier, David Lennon^*

^*Corresponding author for this work

Research output: Contribution to journal › Article

12 Citations (Scopus)

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Abstract

Inelastic neutron scattering (INS) is used to investigate a ZSM-5 catalyst that has been exposed to methanol vapour at elevated temperature. In-line mass spectrometric analysis of the catalyst exit stream confirms methanol-to-gasoline chemistry, whilst ex situ INS measurements detect hydrocarbon species formed in/on the catalyst during methanol conversion. These preliminary studies demonstrate the capability of INS to complement infrared spectroscopic characterisation of the hydrocarbon pool present in/on ZSM-5 during the MTG reaction.

Original language	English
Pages (from-to)	1242-1248
Number of pages	7
Journal	Catalysis Letters
Volume	146
Issue number	7
Early online date	15 Apr 2016
DOIs	https://doi.org/10.1007/s10562-016-1742-5
Publication status	Published - Jul 2016

Keywords

Hydrocarbon pool
Inelastic neutron scattering
Methanol
ZSM-5

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Application of Inelastic Neutron Scattering to the Methanol-to-Gasoline Reaction Over a ZSM-5 Catalyst
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Howe, R. F., McGregor, J., Parker, S. F., Collier, P., & Lennon, D. (2016). Application of Inelastic Neutron Scattering to the Methanol-to-Gasoline Reaction Over a ZSM-5 Catalyst. Catalysis Letters, 146(7), 1242-1248. https://doi.org/10.1007/s10562-016-1742-5

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abstract = "Inelastic neutron scattering (INS) is used to investigate a ZSM-5 catalyst that has been exposed to methanol vapour at elevated temperature. In-line mass spectrometric analysis of the catalyst exit stream confirms methanol-to-gasoline chemistry, whilst ex situ INS measurements detect hydrocarbon species formed in/on the catalyst during methanol conversion. These preliminary studies demonstrate the capability of INS to complement infrared spectroscopic characterisation of the hydrocarbon pool present in/on ZSM-5 during the MTG reaction.",

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note = "The Science and Technology Facilities Council is thanked for the provision of neutron beamtime. The EPSRC and the UK Catalysis Hub are thanked for project support via Grant Numbers EP/I019693/1 and EP/K014854/1.",

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AU - Lennon, David

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