Aqua(dipicolinato-kappa(3) O,N,O ')(1,10-phenanthroline-kappa(2) N,N ')zinc(II) monohydrate

W T A Harrison, P Ramadevi, S Kumaresan

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The title compound, [Zn(C7H3NO4)(C12H8N2)(H2O)]center dot H2O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO3N3 octahedral grouping. The crystal packing is consolidated by O - H center dot center dot center dot O hydrogen bonds and probable pi-pi stacking.

Original languageEnglish
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume62
DOIs
Publication statusPublished - 2006

Keywords

  • HYDROGEN-BONDS
  • COMPLEXES

Cite this

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title = "Aqua(dipicolinato-kappa(3) O,N,O ')(1,10-phenanthroline-kappa(2) N,N ')zinc(II) monohydrate",
abstract = "The title compound, [Zn(C7H3NO4)(C12H8N2)(H2O)]center dot H2O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO3N3 octahedral grouping. The crystal packing is consolidated by O - H center dot center dot center dot O hydrogen bonds and probable pi-pi stacking.",
keywords = "HYDROGEN-BONDS, COMPLEXES",
author = "Harrison, {W T A} and P Ramadevi and S Kumaresan",
year = "2006",
doi = "10.1107/S160053680600420X",
language = "English",
volume = "62",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Aqua(dipicolinato-kappa(3) O,N,O ')(1,10-phenanthroline-kappa(2) N,N ')zinc(II) monohydrate

AU - Harrison, W T A

AU - Ramadevi, P

AU - Kumaresan, S

PY - 2006

Y1 - 2006

N2 - The title compound, [Zn(C7H3NO4)(C12H8N2)(H2O)]center dot H2O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO3N3 octahedral grouping. The crystal packing is consolidated by O - H center dot center dot center dot O hydrogen bonds and probable pi-pi stacking.

AB - The title compound, [Zn(C7H3NO4)(C12H8N2)(H2O)]center dot H2O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO3N3 octahedral grouping. The crystal packing is consolidated by O - H center dot center dot center dot O hydrogen bonds and probable pi-pi stacking.

KW - HYDROGEN-BONDS

KW - COMPLEXES

U2 - 10.1107/S160053680600420X

DO - 10.1107/S160053680600420X

M3 - Article

VL - 62

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

ER -