Aqua(dipicolinato-kappa(3) O,N,O ')(1,10-phenanthroline-kappa(2) N,N ')zinc(II) monohydrate

W T A  Harrison; P  Ramadevi; S  Kumaresan

doi:10.1107/S160053680600420X

Aqua(dipicolinato-kappa(3) O,N,O ')(1,10-phenanthroline-kappa(2) N,N ')zinc(II) monohydrate

W T A Harrison, P Ramadevi, S Kumaresan

Chemistry

Research output: Contribution to journal › Article

13 Citations (Scopus)

Abstract

The title compound, [Zn(C7H3NO4)(C12H8N2)(H2O)]center dot H2O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO3N3 octahedral grouping. The crystal packing is consolidated by O - H center dot center dot center dot O hydrogen bonds and probable pi-pi stacking.

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
DOIs	https://doi.org/10.1107/S160053680600420X
Publication status	Published - 2006

Keywords

HYDROGEN-BONDS
COMPLEXES

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10.1107/S160053680600420X

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title = "Aqua(dipicolinato-kappa(3) O,N,O ')(1,10-phenanthroline-kappa(2) N,N ')zinc(II) monohydrate",

abstract = "The title compound, [Zn(C7H3NO4)(C12H8N2)(H2O)]center dot H2O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO3N3 octahedral grouping. The crystal packing is consolidated by O - H center dot center dot center dot O hydrogen bonds and probable pi-pi stacking.",

keywords = "HYDROGEN-BONDS, COMPLEXES",

author = "Harrison, {W T A} and P Ramadevi and S Kumaresan",

year = "2006",

doi = "10.1107/S160053680600420X",

language = "English",

volume = "62",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Aqua(dipicolinato-kappa(3) O,N,O ')(1,10-phenanthroline-kappa(2) N,N ')zinc(II) monohydrate

AU - Harrison, W T A

AU - Ramadevi, P

AU - Kumaresan, S

PY - 2006

Y1 - 2006

N2 - The title compound, [Zn(C7H3NO4)(C12H8N2)(H2O)]center dot H2O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO3N3 octahedral grouping. The crystal packing is consolidated by O - H center dot center dot center dot O hydrogen bonds and probable pi-pi stacking.

AB - The title compound, [Zn(C7H3NO4)(C12H8N2)(H2O)]center dot H2O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO3N3 octahedral grouping. The crystal packing is consolidated by O - H center dot center dot center dot O hydrogen bonds and probable pi-pi stacking.

KW - HYDROGEN-BONDS

KW - COMPLEXES

U2 - 10.1107/S160053680600420X

DO - 10.1107/S160053680600420X

M3 - Article

VL - 62

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

ER -

Aqua(dipicolinato-kappa(3) O,N,O ')(1,10-phenanthroline-kappa(2) N,N ')zinc(II) monohydrate

Abstract

Keywords

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