Attenuated Total Reflection Infrared Difference Spectroscopy (ATR-IRDS) for Quantitative Reaction Monitoring

Johannes Kiefer, Melek A. Coengevel, Daniel Roth, Katharina Obert, Peter Wasserscheid, Alfred Leipertz

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Monitoring of chemical reactors is key to optimizing yield and efficiency of chemical transformation processes. Aside from tracking pressure and temperature, the measurement of the chemical composition is essential in this context. We present an infrared difference spectroscopy approach for determining the reactant (cyclooctene) and product (cyclooctane) concentrations during a catalytic hydrogenation reaction in the solvent cyclohexane, which is present in large excess. Subtracting the spectrum of the pure solvent from the reactor mixture spectra yields infrared (IR) spectra, which can ultimately be evaluated using a curve-fitting procedure based on spectral soft modeling. An important feature of our evaluation approach is that the calibration only requires recording the pure component spectra of the reactants, products, and solvent. Hence, no time-consuming preparation of mixtures for calibration is necessary. The IR concentration results are in good agreement with gas chromatography measurements.
Original languageEnglish
Pages (from-to)685-688
Number of pages4
JournalApplied Spectroscopy
Volume66
Issue number6
Early online date9 May 2012
DOIs
Publication statusPublished - 1 Jun 2012

Keywords

  • attenuated total reflection spectroscopy
  • ATR
  • Fourier transform infrared spectroscopy
  • FT-IR
  • hydrogenation
  • difference spectroscopy
  • quantitative measurement
  • catalysis

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    Kiefer, J., Coengevel, M. A., Roth, D., Obert, K., Wasserscheid, P., & Leipertz, A. (2012). Attenuated Total Reflection Infrared Difference Spectroscopy (ATR-IRDS) for Quantitative Reaction Monitoring. Applied Spectroscopy, 66(6), 685-688. https://doi.org/10.1366/11-06472