Bis(1-carbamoylguanidinium) diaquatetrachloromanganate(II)

C A Bremner, W T A Harrison

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The title compound, (C2H7N4O)(2)[MnCl4(H2O)(2)], contains a molecular network of C2H7N4O+ cations and [Mn(H2O)(2)Cl-4](2-) trans-octahedral anions (Mn site symmetry 2/m). An extensive network of N - H...Cl, N - H...(Cl,Cl), N - H...O, O - H...O and O - H...Cl links results in a structure with a three-dimensional hydrogen-bonding network. The compound is isostructural with its copper- and cobalt-containing congeners.

Original languageEnglish
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
DOIs
Publication statusPublished - 2003

Cite this

Bis(1-carbamoylguanidinium) diaquatetrachloromanganate(II). / Bremner, C A ; Harrison, W T A .

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 59, 2003.

Research output: Contribution to journalArticle

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abstract = "The title compound, (C2H7N4O)(2)[MnCl4(H2O)(2)], contains a molecular network of C2H7N4O+ cations and [Mn(H2O)(2)Cl-4](2-) trans-octahedral anions (Mn site symmetry 2/m). An extensive network of N - H...Cl, N - H...(Cl,Cl), N - H...O, O - H...O and O - H...Cl links results in a structure with a three-dimensional hydrogen-bonding network. The compound is isostructural with its copper- and cobalt-containing congeners.",
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N2 - The title compound, (C2H7N4O)(2)[MnCl4(H2O)(2)], contains a molecular network of C2H7N4O+ cations and [Mn(H2O)(2)Cl-4](2-) trans-octahedral anions (Mn site symmetry 2/m). An extensive network of N - H...Cl, N - H...(Cl,Cl), N - H...O, O - H...O and O - H...Cl links results in a structure with a three-dimensional hydrogen-bonding network. The compound is isostructural with its copper- and cobalt-containing congeners.

AB - The title compound, (C2H7N4O)(2)[MnCl4(H2O)(2)], contains a molecular network of C2H7N4O+ cations and [Mn(H2O)(2)Cl-4](2-) trans-octahedral anions (Mn site symmetry 2/m). An extensive network of N - H...Cl, N - H...(Cl,Cl), N - H...O, O - H...O and O - H...Cl links results in a structure with a three-dimensional hydrogen-bonding network. The compound is isostructural with its copper- and cobalt-containing congeners.

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JO - Acta Crystallographica Section E: Structure Reports Online

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