Bis(1,2,3,5-tetramethyl-4-nitropyrazolium) dihydronium tris(4-methyl-3,5-dinitrobenzenesulfonate) forms C(8) chains through O-H center dot center dot center dot O bonding via the dihydronium cation

J M S Skakle, J L Wardell

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

In the title salt, 2C(7)H(12)N(3)O(2)(+.)H(5)O(2)(+.)3C(7)H(5)N(2)O(7)S(-), strong hydrogen bonding from the donor (H5O2+) group links to 4-methyl-3,5-dinitrobenzenesulfonate anions. The dihydronium (H5O2+) cation could be considered intermediate between clearly distinct (H3O)(+) and H2O entities and an '(H5O2)(+)' entity, although it tends to be closer to the former; the (OO)-O-... distance is 2.434 (3) angstrom. Strong hydrogen bonding leads to the formation of chains along the [ 010] direction.

Original languageEnglish
Pages (from-to)o1402-o1404
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume62
Issue number4
DOIs
Publication statusPublished - Apr 2006

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Cations
Hydrogen bonds
Positive ions
cations
hydrogen
Anions
Negative ions
Salts
anions
salts
Direction compound

Keywords

  • hydrogen

Cite this

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title = "Bis(1,2,3,5-tetramethyl-4-nitropyrazolium) dihydronium tris(4-methyl-3,5-dinitrobenzenesulfonate) forms C(8) chains through O-H center dot center dot center dot O bonding via the dihydronium cation",
abstract = "In the title salt, 2C(7)H(12)N(3)O(2)(+.)H(5)O(2)(+.)3C(7)H(5)N(2)O(7)S(-), strong hydrogen bonding from the donor (H5O2+) group links to 4-methyl-3,5-dinitrobenzenesulfonate anions. The dihydronium (H5O2+) cation could be considered intermediate between clearly distinct (H3O)(+) and H2O entities and an '(H5O2)(+)' entity, although it tends to be closer to the former; the (OO)-O-... distance is 2.434 (3) angstrom. Strong hydrogen bonding leads to the formation of chains along the [ 010] direction.",
keywords = "hydrogen",
author = "Skakle, {J M S} and Wardell, {J L}",
year = "2006",
month = "4",
doi = "10.1107/S1600536806008749",
language = "English",
volume = "62",
pages = "o1402--o1404",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "4",

}

TY - JOUR

T1 - Bis(1,2,3,5-tetramethyl-4-nitropyrazolium) dihydronium tris(4-methyl-3,5-dinitrobenzenesulfonate) forms C(8) chains through O-H center dot center dot center dot O bonding via the dihydronium cation

AU - Skakle, J M S

AU - Wardell, J L

PY - 2006/4

Y1 - 2006/4

N2 - In the title salt, 2C(7)H(12)N(3)O(2)(+.)H(5)O(2)(+.)3C(7)H(5)N(2)O(7)S(-), strong hydrogen bonding from the donor (H5O2+) group links to 4-methyl-3,5-dinitrobenzenesulfonate anions. The dihydronium (H5O2+) cation could be considered intermediate between clearly distinct (H3O)(+) and H2O entities and an '(H5O2)(+)' entity, although it tends to be closer to the former; the (OO)-O-... distance is 2.434 (3) angstrom. Strong hydrogen bonding leads to the formation of chains along the [ 010] direction.

AB - In the title salt, 2C(7)H(12)N(3)O(2)(+.)H(5)O(2)(+.)3C(7)H(5)N(2)O(7)S(-), strong hydrogen bonding from the donor (H5O2+) group links to 4-methyl-3,5-dinitrobenzenesulfonate anions. The dihydronium (H5O2+) cation could be considered intermediate between clearly distinct (H3O)(+) and H2O entities and an '(H5O2)(+)' entity, although it tends to be closer to the former; the (OO)-O-... distance is 2.434 (3) angstrom. Strong hydrogen bonding leads to the formation of chains along the [ 010] direction.

KW - hydrogen

U2 - 10.1107/S1600536806008749

DO - 10.1107/S1600536806008749

M3 - Article

VL - 62

SP - o1402-o1404

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 4

ER -