Bis(1,3-dithiole-2-one-4,5-dithiolato)antimonite(1-)salts, [Q][Sb(dmio)2]. Structural comparisons of [Q][Sb(dmio)2] and bis(1,3-dithiole-2-thione-4,5-dithiolato)antimonite(1-) salts, [!][Sb(dmit)2]

J. H. Aupers, Z. H. Chohan, N. M. Comerlato, Robert Alan Howie, A. C. Silvino, J. L. Wardell, S. M. S. V. Wardell

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Bis(1,3-dithiole-2-one-4,5-dithiolato)antimonate(1-) salts, [Q][Sb(C3OS4)(2)], [Q][Sb(dmio)(2)] (3: Q = NEt4, 1,4-dimethylpyridinium (DMP), PPh4 or ferrocenyl-CH2NMe3) and bis(1,3-dithiole-2-thione-4,5-dithiolato)antimonate(1-) salts, [Q][Sb(C3S5)(2)], [Q][Sb(dmit)(2)] (1: Q = AsPh4 or NBu4) have been obtained from SbBr3-NaSCN and [Q](2)[Zn(dmio)(2)]or [Q](2)[Zn(dmio)(2)]. The crystal structures of (1: Q = AsPh4 or NBu4) and (3: Q = NEt4 and DMP) have been determined. In all cases, the Sb centres are 6-coordinated and, with the inclusion of the lone pair, are considered to have pseudo pentagonal bipyramidal structures. The interanion interactions in these and related complexes are compared. (C) 2002 Elsevier Science Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)2107-2116
Number of pages9
JournalPolyhedron
Volume21
DOIs
Publication statusPublished - 2002

Keywords

  • 1,3-dithiole-2-thione-4,5-dithiolates
  • 1,3-dithiole-2-one-4,5-dithiolates
  • antimony(III)
  • crystal structures
  • ANTIMONY(III) BIS-DMIT
  • = ONIUM CATION
  • CRYSTAL-STRUCTURES
  • COORDINATION CHEMISTRY
  • COMPLEXES
  • TETRAETHYLAMMONIUM
  • PSEUDOHALIDE
  • HALIDE

Cite this

Bis(1,3-dithiole-2-one-4,5-dithiolato)antimonite(1-)salts, [Q][Sb(dmio)2]. Structural comparisons of [Q][Sb(dmio)2] and bis(1,3-dithiole-2-thione-4,5-dithiolato)antimonite(1-) salts, [!][Sb(dmit)2]. / Aupers, J. H.; Chohan, Z. H.; Comerlato, N. M.; Howie, Robert Alan; Silvino, A. C.; Wardell, J. L.; Wardell, S. M. S. V.

In: Polyhedron, Vol. 21, 2002, p. 2107-2116.

Research output: Contribution to journalArticle

Aupers, J. H. ; Chohan, Z. H. ; Comerlato, N. M. ; Howie, Robert Alan ; Silvino, A. C. ; Wardell, J. L. ; Wardell, S. M. S. V. / Bis(1,3-dithiole-2-one-4,5-dithiolato)antimonite(1-)salts, [Q][Sb(dmio)2]. Structural comparisons of [Q][Sb(dmio)2] and bis(1,3-dithiole-2-thione-4,5-dithiolato)antimonite(1-) salts, [!][Sb(dmit)2]. In: Polyhedron. 2002 ; Vol. 21. pp. 2107-2116.
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abstract = "Bis(1,3-dithiole-2-one-4,5-dithiolato)antimonate(1-) salts, [Q][Sb(C3OS4)(2)], [Q][Sb(dmio)(2)] (3: Q = NEt4, 1,4-dimethylpyridinium (DMP), PPh4 or ferrocenyl-CH2NMe3) and bis(1,3-dithiole-2-thione-4,5-dithiolato)antimonate(1-) salts, [Q][Sb(C3S5)(2)], [Q][Sb(dmit)(2)] (1: Q = AsPh4 or NBu4) have been obtained from SbBr3-NaSCN and [Q](2)[Zn(dmio)(2)]or [Q](2)[Zn(dmio)(2)]. The crystal structures of (1: Q = AsPh4 or NBu4) and (3: Q = NEt4 and DMP) have been determined. In all cases, the Sb centres are 6-coordinated and, with the inclusion of the lone pair, are considered to have pseudo pentagonal bipyramidal structures. The interanion interactions in these and related complexes are compared. (C) 2002 Elsevier Science Ltd. All rights reserved.",
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T1 - Bis(1,3-dithiole-2-one-4,5-dithiolato)antimonite(1-)salts, [Q][Sb(dmio)2]. Structural comparisons of [Q][Sb(dmio)2] and bis(1,3-dithiole-2-thione-4,5-dithiolato)antimonite(1-) salts, [!][Sb(dmit)2]

AU - Aupers, J. H.

AU - Chohan, Z. H.

AU - Comerlato, N. M.

AU - Howie, Robert Alan

AU - Silvino, A. C.

AU - Wardell, J. L.

AU - Wardell, S. M. S. V.

PY - 2002

Y1 - 2002

N2 - Bis(1,3-dithiole-2-one-4,5-dithiolato)antimonate(1-) salts, [Q][Sb(C3OS4)(2)], [Q][Sb(dmio)(2)] (3: Q = NEt4, 1,4-dimethylpyridinium (DMP), PPh4 or ferrocenyl-CH2NMe3) and bis(1,3-dithiole-2-thione-4,5-dithiolato)antimonate(1-) salts, [Q][Sb(C3S5)(2)], [Q][Sb(dmit)(2)] (1: Q = AsPh4 or NBu4) have been obtained from SbBr3-NaSCN and [Q](2)[Zn(dmio)(2)]or [Q](2)[Zn(dmio)(2)]. The crystal structures of (1: Q = AsPh4 or NBu4) and (3: Q = NEt4 and DMP) have been determined. In all cases, the Sb centres are 6-coordinated and, with the inclusion of the lone pair, are considered to have pseudo pentagonal bipyramidal structures. The interanion interactions in these and related complexes are compared. (C) 2002 Elsevier Science Ltd. All rights reserved.

AB - Bis(1,3-dithiole-2-one-4,5-dithiolato)antimonate(1-) salts, [Q][Sb(C3OS4)(2)], [Q][Sb(dmio)(2)] (3: Q = NEt4, 1,4-dimethylpyridinium (DMP), PPh4 or ferrocenyl-CH2NMe3) and bis(1,3-dithiole-2-thione-4,5-dithiolato)antimonate(1-) salts, [Q][Sb(C3S5)(2)], [Q][Sb(dmit)(2)] (1: Q = AsPh4 or NBu4) have been obtained from SbBr3-NaSCN and [Q](2)[Zn(dmio)(2)]or [Q](2)[Zn(dmio)(2)]. The crystal structures of (1: Q = AsPh4 or NBu4) and (3: Q = NEt4 and DMP) have been determined. In all cases, the Sb centres are 6-coordinated and, with the inclusion of the lone pair, are considered to have pseudo pentagonal bipyramidal structures. The interanion interactions in these and related complexes are compared. (C) 2002 Elsevier Science Ltd. All rights reserved.

KW - 1,3-dithiole-2-thione-4,5-dithiolates

KW - 1,3-dithiole-2-one-4,5-dithiolates

KW - antimony(III)

KW - crystal structures

KW - ANTIMONY(III) BIS-DMIT

KW - = ONIUM CATION

KW - CRYSTAL-STRUCTURES

KW - COORDINATION CHEMISTRY

KW - COMPLEXES

KW - TETRAETHYLAMMONIUM

KW - PSEUDOHALIDE

KW - HALIDE

U2 - 10.1016/S0277-5387(02)01156-7

DO - 10.1016/S0277-5387(02)01156-7

M3 - Article

VL - 21

SP - 2107

EP - 2116

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -