Bis(acetonitrile-kappa N)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazatetradecane-kappa N-4]copper(II) bis{tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate} 0.31-hydrate

J M S Skakle, M V D R E Silva, J L Wardell, S M S V Wardell

Research output: Contribution to journalArticle

Abstract

The title compound, [Cu(C2H3N)(2)(C10H24N4)](C32H12BF24)(2).0.31H(2)O, crystallizes as an ionic species with no interactions between the ions. The [Cu-II(cyclam)(MeCN)(2)](2+) dication (cyclam is 1,4,8,11-tetraazatetradecane), located on a 2/m symmetry site, forms as a distorted octahedral species with four Cu-N-cyclam bonds of 2.013 (2) Angstrom and two C-N-MeCN bonds of 2.499 (4) Angstrom. The [B{C6H3(CF3)- 3,5}(4)](-) anion, located on a twofold axis, is a distorted octahedral species. A small amount of water is present, occupying sites between columns of ions.

Original languageEnglish
Pages (from-to)m413-m415
Number of pages3
JournalActa Crystallographica Section C, Crystal Structure Communications
VolumeC59
Issue number10
DOIs
Publication statusPublished - 2003

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Hydrates
Copper
Ions
Anions
Water
acetonitrile
cyclam
tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

Keywords

  • molecular-structure
  • crystal-structure
  • copper(II)
  • complexes

Cite this

@article{d336133d191a49119787491d4d54cd68,
title = "Bis(acetonitrile-kappa N)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazatetradecane-kappa N-4]copper(II) bis{tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate} 0.31-hydrate",
abstract = "The title compound, [Cu(C2H3N)(2)(C10H24N4)](C32H12BF24)(2).0.31H(2)O, crystallizes as an ionic species with no interactions between the ions. The [Cu-II(cyclam)(MeCN)(2)](2+) dication (cyclam is 1,4,8,11-tetraazatetradecane), located on a 2/m symmetry site, forms as a distorted octahedral species with four Cu-N-cyclam bonds of 2.013 (2) Angstrom and two C-N-MeCN bonds of 2.499 (4) Angstrom. The [B{C6H3(CF3)- 3,5}(4)](-) anion, located on a twofold axis, is a distorted octahedral species. A small amount of water is present, occupying sites between columns of ions.",
keywords = "molecular-structure, crystal-structure, copper(II), complexes",
author = "Skakle, {J M S} and Silva, {M V D R E} and Wardell, {J L} and Wardell, {S M S V}",
year = "2003",
doi = "10.1107/S0108270103016743",
language = "English",
volume = "C59",
pages = "m413--m415",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",
number = "10",

}

TY - JOUR

T1 - Bis(acetonitrile-kappa N)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazatetradecane-kappa N-4]copper(II) bis{tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate} 0.31-hydrate

AU - Skakle, J M S

AU - Silva, M V D R E

AU - Wardell, J L

AU - Wardell, S M S V

PY - 2003

Y1 - 2003

N2 - The title compound, [Cu(C2H3N)(2)(C10H24N4)](C32H12BF24)(2).0.31H(2)O, crystallizes as an ionic species with no interactions between the ions. The [Cu-II(cyclam)(MeCN)(2)](2+) dication (cyclam is 1,4,8,11-tetraazatetradecane), located on a 2/m symmetry site, forms as a distorted octahedral species with four Cu-N-cyclam bonds of 2.013 (2) Angstrom and two C-N-MeCN bonds of 2.499 (4) Angstrom. The [B{C6H3(CF3)- 3,5}(4)](-) anion, located on a twofold axis, is a distorted octahedral species. A small amount of water is present, occupying sites between columns of ions.

AB - The title compound, [Cu(C2H3N)(2)(C10H24N4)](C32H12BF24)(2).0.31H(2)O, crystallizes as an ionic species with no interactions between the ions. The [Cu-II(cyclam)(MeCN)(2)](2+) dication (cyclam is 1,4,8,11-tetraazatetradecane), located on a 2/m symmetry site, forms as a distorted octahedral species with four Cu-N-cyclam bonds of 2.013 (2) Angstrom and two C-N-MeCN bonds of 2.499 (4) Angstrom. The [B{C6H3(CF3)- 3,5}(4)](-) anion, located on a twofold axis, is a distorted octahedral species. A small amount of water is present, occupying sites between columns of ions.

KW - molecular-structure

KW - crystal-structure

KW - copper(II)

KW - complexes

U2 - 10.1107/S0108270103016743

DO - 10.1107/S0108270103016743

M3 - Article

VL - C59

SP - m413-m415

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

IS - 10

ER -