Bis(cyanido-κC)bis­­(cyclo­hexyl­amine-κN)mercury(II)

Missing Ejaz; Islam Ullah Khan; William T. A. Harrison

doi:10.1107/S1600536810001042

Bis(cyanido-κC)bis(cyclohexylamine-κN)mercury(II)

Missing Ejaz, Islam Ullah Khan, William T. A. Harrison

Chemistry

Mat Chem Lab

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, [Hg(CN)₂(C₆H₁₃N)₂], the Hg^II ion adopts an extremely distorted HgC₂N₂ tetrahedral coordination. The crystal packing is influenced by weak N—H⋯N hydrogen bonds between the amino groups and the cyanide N atoms, resulting in chains of molecules propagating in [110]. Both cyclohexylamine molecules adopt chair conformations.

Original language	English
Pages (from-to)	M238-U1409
Number of pages	10
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
DOIs	https://doi.org/10.1107/S1600536810001042
Publication status	Published - Feb 2010

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@article{5ca33388ff9c4f43899f7ec1911d91a3,

title = "Bis(cyanido-κC)bis(cyclohexylamine-κN)mercury(II)",

abstract = "In the title compound, [Hg(CN)2(C6H13N)2], the HgII ion adopts an extremely distorted HgC2N2 tetrahedral coordination. The crystal packing is influenced by weak N—H⋯N hydrogen bonds between the amino groups and the cyanide N atoms, resulting in chains of molecules propagating in [110]. Both cyclohexylamine molecules adopt chair conformations.",

author = "Missing Ejaz and Khan, {Islam Ullah} and Harrison, {William T. A.}",

year = "2010",

month = feb,

doi = "10.1107/S1600536810001042",

language = "English",

volume = "66",

pages = "M238--U1409",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Bis(cyanido-κC)bis(cyclohexylamine-κN)mercury(II)

AU - Ejaz, Missing

AU - Khan, Islam Ullah

AU - Harrison, William T. A.

PY - 2010/2

Y1 - 2010/2

N2 - In the title compound, [Hg(CN)2(C6H13N)2], the HgII ion adopts an extremely distorted HgC2N2 tetrahedral coordination. The crystal packing is influenced by weak N—H⋯N hydrogen bonds between the amino groups and the cyanide N atoms, resulting in chains of molecules propagating in [110]. Both cyclohexylamine molecules adopt chair conformations.

AB - In the title compound, [Hg(CN)2(C6H13N)2], the HgII ion adopts an extremely distorted HgC2N2 tetrahedral coordination. The crystal packing is influenced by weak N—H⋯N hydrogen bonds between the amino groups and the cyanide N atoms, resulting in chains of molecules propagating in [110]. Both cyclohexylamine molecules adopt chair conformations.

U2 - 10.1107/S1600536810001042

DO - 10.1107/S1600536810001042

M3 - Article

SN - 1600-5368

VL - 66

SP - M238-U1409

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

ER -

Bis(cyanido-κC)bis­­(cyclo­hexyl­amine-κN)mercury(II)

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Bis(cyanido-κC)bis(cyclohexylamine-κN)mercury(II)