Bis(guanidinium) diaquapentakis(nitrato-kappa O-2,O ')-lanthanum

A  Fowkes; W T A  Harrison

doi:10.1107/S1600536804025255

Bis(guanidinium) diaquapentakis(nitrato-kappa O-2,O ')-lanthanum

A Fowkes, W T A Harrison

Chemistry

Research output: Contribution to journal › Article

3 Citations (Scopus)

Abstract

The title compound, (CH6N3)(2)[La(NO3)(5)(H2O)(2)], contains a network of guanidinium cations and the previously unseen diaquapentakis(nitrato)lanthanum dianion, in which 12 O atoms surround La in a distorted icosahedral arrangement. A network of N-H...O and O-H...O hydrogen bonds helps to consolidate the crystal packing, resulting in a three-dimensional network. The La cation, one N atom and one O atom occupy a twofold axis.

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
DOIs	https://doi.org/10.1107/S1600536804025255
Publication status	Published - 2004

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title = "Bis(guanidinium) diaquapentakis(nitrato-kappa O-2,O ')-lanthanum",

abstract = "The title compound, (CH6N3)(2)[La(NO3)(5)(H2O)(2)], contains a network of guanidinium cations and the previously unseen diaquapentakis(nitrato)lanthanum dianion, in which 12 O atoms surround La in a distorted icosahedral arrangement. A network of N-H...O and O-H...O hydrogen bonds helps to consolidate the crystal packing, resulting in a three-dimensional network. The La cation, one N atom and one O atom occupy a twofold axis.",

author = "A Fowkes and Harrison, {W T A}",

year = "2004",

doi = "10.1107/S1600536804025255",

language = "English",

volume = "60",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Bis(guanidinium) diaquapentakis(nitrato-kappa O-2,O ')-lanthanum

AU - Fowkes, A

AU - Harrison, W T A

PY - 2004

Y1 - 2004

N2 - The title compound, (CH6N3)(2)[La(NO3)(5)(H2O)(2)], contains a network of guanidinium cations and the previously unseen diaquapentakis(nitrato)lanthanum dianion, in which 12 O atoms surround La in a distorted icosahedral arrangement. A network of N-H...O and O-H...O hydrogen bonds helps to consolidate the crystal packing, resulting in a three-dimensional network. The La cation, one N atom and one O atom occupy a twofold axis.

AB - The title compound, (CH6N3)(2)[La(NO3)(5)(H2O)(2)], contains a network of guanidinium cations and the previously unseen diaquapentakis(nitrato)lanthanum dianion, in which 12 O atoms surround La in a distorted icosahedral arrangement. A network of N-H...O and O-H...O hydrogen bonds helps to consolidate the crystal packing, resulting in a three-dimensional network. The La cation, one N atom and one O atom occupy a twofold axis.

U2 - 10.1107/S1600536804025255

DO - 10.1107/S1600536804025255

M3 - Article

VL - 60

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

ER -

Bis(guanidinium) diaquapentakis(nitrato-kappa O-2,O ')-lanthanum

Abstract

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