Bis(homopiperazinium) diaquapentakis(nitrato-kappa O-2,O ')lanthanate(III) dinitrate

Research output: Contribution to journalArticle

Abstract

The title compound, (C5H14N2)(2)[La(NO3)(5)(H2O)(2)](NO3)(2), contains a network of doubly protonated homopiperazinium (1,4-diazo-niacyclo-hepta-ne) cations, diaqua-penta-nitrato-lan-thanate(III) dianions and nitrate anions. In the complex anion, the 12 O atoms surround La in a distorted icosa-hedral arrangement. A network of N-HcO and O-HcO hydrogen bonds help to consolidate the crystal packing, resulting in a three-dimensional network. The La atom and one N and one O atom lie on a twofold axis.

Original languageEnglish
Pages (from-to)m1301-m1303
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
VolumeE62
Issue number6
DOIs
Publication statusPublished - Jun 2006

Cite this

@article{d97fd859dcf443dca3c8b38daeacefda,
title = "Bis(homopiperazinium) diaquapentakis(nitrato-kappa O-2,O ')lanthanate(III) dinitrate",
abstract = "The title compound, (C5H14N2)(2)[La(NO3)(5)(H2O)(2)](NO3)(2), contains a network of doubly protonated homopiperazinium (1,4-diazo-niacyclo-hepta-ne) cations, diaqua-penta-nitrato-lan-thanate(III) dianions and nitrate anions. In the complex anion, the 12 O atoms surround La in a distorted icosa-hedral arrangement. A network of N-HcO and O-HcO hydrogen bonds help to consolidate the crystal packing, resulting in a three-dimensional network. The La atom and one N and one O atom lie on a twofold axis.",
author = "A Fowkes and Harrison, {William Thomas Alexander}",
year = "2006",
month = "6",
doi = "10.1107/S1600536806017235",
language = "English",
volume = "E62",
pages = "m1301--m1303",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "6",

}

TY - JOUR

T1 - Bis(homopiperazinium) diaquapentakis(nitrato-kappa O-2,O ')lanthanate(III) dinitrate

AU - Fowkes, A

AU - Harrison, William Thomas Alexander

PY - 2006/6

Y1 - 2006/6

N2 - The title compound, (C5H14N2)(2)[La(NO3)(5)(H2O)(2)](NO3)(2), contains a network of doubly protonated homopiperazinium (1,4-diazo-niacyclo-hepta-ne) cations, diaqua-penta-nitrato-lan-thanate(III) dianions and nitrate anions. In the complex anion, the 12 O atoms surround La in a distorted icosa-hedral arrangement. A network of N-HcO and O-HcO hydrogen bonds help to consolidate the crystal packing, resulting in a three-dimensional network. The La atom and one N and one O atom lie on a twofold axis.

AB - The title compound, (C5H14N2)(2)[La(NO3)(5)(H2O)(2)](NO3)(2), contains a network of doubly protonated homopiperazinium (1,4-diazo-niacyclo-hepta-ne) cations, diaqua-penta-nitrato-lan-thanate(III) dianions and nitrate anions. In the complex anion, the 12 O atoms surround La in a distorted icosa-hedral arrangement. A network of N-HcO and O-HcO hydrogen bonds help to consolidate the crystal packing, resulting in a three-dimensional network. The La atom and one N and one O atom lie on a twofold axis.

U2 - 10.1107/S1600536806017235

DO - 10.1107/S1600536806017235

M3 - Article

VL - E62

SP - m1301-m1303

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 6

ER -