Bis(p-nitrobenzoxasulfamato) complexes of cadmium(II) and mercury(II) - Synthesis, spectra, and X-ray crystal structures

V T Yilmaz, T K Yazicilar, O Andac, H Kutuk, Y Bekdemir, W T A Harrison

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The reaction of sodium benzoxasulfamate (ribs) with cadmium(II) and mercury(II) sulfate in aqueous solution yield the novel complexes [Cd(nbs)(2)(H2O)(4)] (1) and [Hg(nbs)(2)(H2O)(3)] (2), respectively. The complexes were characterized by elemental analyses, IR spectroscopy and X-ray crystallography. Complex 1 is monomeric and has an octahedral arrangement in which the N-donor ribs ligands occupy the axial positions, while the water oxygen atoms form the equatorial plane. Complex 2 is polymeric and shows a pentagonal bipyramidal arrangement achieved by the bridging of the HgN2O3 units through the weak interaction of the O atoms of the nitro group. The ribs ligands also occupy the axial positions of the pentagonal bipyramid, whereas three water and two nitro oxygen atoms constitute the pentagonal plane. The crystal structure packing in both crystals is achieved by the intermolecular hydrogen bonds involving water hydrogen atoms, nitro and sulfonyl oxygen atoms.

Original languageEnglish
Pages (from-to)1908-1912
Number of pages5
JournalZeitschrift für Anorganische und Allgemeine Chemie
Volume628
Publication statusPublished - 2002

Keywords

  • p-nitrobenzoxasulfamate
  • cadmium(II)
  • mercury(II)
  • crystal structures
  • PI-COMPLEXES
  • SULFAMATE
  • SACCHARINATE

Cite this

Bis(p-nitrobenzoxasulfamato) complexes of cadmium(II) and mercury(II) - Synthesis, spectra, and X-ray crystal structures. / Yilmaz, V T ; Yazicilar, T K ; Andac, O ; Kutuk, H ; Bekdemir, Y ; Harrison, W T A .

In: Zeitschrift für Anorganische und Allgemeine Chemie, Vol. 628, 2002, p. 1908-1912.

Research output: Contribution to journalArticle

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abstract = "The reaction of sodium benzoxasulfamate (ribs) with cadmium(II) and mercury(II) sulfate in aqueous solution yield the novel complexes [Cd(nbs)(2)(H2O)(4)] (1) and [Hg(nbs)(2)(H2O)(3)] (2), respectively. The complexes were characterized by elemental analyses, IR spectroscopy and X-ray crystallography. Complex 1 is monomeric and has an octahedral arrangement in which the N-donor ribs ligands occupy the axial positions, while the water oxygen atoms form the equatorial plane. Complex 2 is polymeric and shows a pentagonal bipyramidal arrangement achieved by the bridging of the HgN2O3 units through the weak interaction of the O atoms of the nitro group. The ribs ligands also occupy the axial positions of the pentagonal bipyramid, whereas three water and two nitro oxygen atoms constitute the pentagonal plane. The crystal structure packing in both crystals is achieved by the intermolecular hydrogen bonds involving water hydrogen atoms, nitro and sulfonyl oxygen atoms.",
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T1 - Bis(p-nitrobenzoxasulfamato) complexes of cadmium(II) and mercury(II) - Synthesis, spectra, and X-ray crystal structures

AU - Yilmaz, V T

AU - Yazicilar, T K

AU - Andac, O

AU - Kutuk, H

AU - Bekdemir, Y

AU - Harrison, W T A

PY - 2002

Y1 - 2002

N2 - The reaction of sodium benzoxasulfamate (ribs) with cadmium(II) and mercury(II) sulfate in aqueous solution yield the novel complexes [Cd(nbs)(2)(H2O)(4)] (1) and [Hg(nbs)(2)(H2O)(3)] (2), respectively. The complexes were characterized by elemental analyses, IR spectroscopy and X-ray crystallography. Complex 1 is monomeric and has an octahedral arrangement in which the N-donor ribs ligands occupy the axial positions, while the water oxygen atoms form the equatorial plane. Complex 2 is polymeric and shows a pentagonal bipyramidal arrangement achieved by the bridging of the HgN2O3 units through the weak interaction of the O atoms of the nitro group. The ribs ligands also occupy the axial positions of the pentagonal bipyramid, whereas three water and two nitro oxygen atoms constitute the pentagonal plane. The crystal structure packing in both crystals is achieved by the intermolecular hydrogen bonds involving water hydrogen atoms, nitro and sulfonyl oxygen atoms.

AB - The reaction of sodium benzoxasulfamate (ribs) with cadmium(II) and mercury(II) sulfate in aqueous solution yield the novel complexes [Cd(nbs)(2)(H2O)(4)] (1) and [Hg(nbs)(2)(H2O)(3)] (2), respectively. The complexes were characterized by elemental analyses, IR spectroscopy and X-ray crystallography. Complex 1 is monomeric and has an octahedral arrangement in which the N-donor ribs ligands occupy the axial positions, while the water oxygen atoms form the equatorial plane. Complex 2 is polymeric and shows a pentagonal bipyramidal arrangement achieved by the bridging of the HgN2O3 units through the weak interaction of the O atoms of the nitro group. The ribs ligands also occupy the axial positions of the pentagonal bipyramid, whereas three water and two nitro oxygen atoms constitute the pentagonal plane. The crystal structure packing in both crystals is achieved by the intermolecular hydrogen bonds involving water hydrogen atoms, nitro and sulfonyl oxygen atoms.

KW - p-nitrobenzoxasulfamate

KW - cadmium(II)

KW - mercury(II)

KW - crystal structures

KW - PI-COMPLEXES

KW - SULFAMATE

KW - SACCHARINATE

M3 - Article

VL - 628

SP - 1908

EP - 1912

JO - Zeitschrift für Anorganische und Allgemeine Chemie

JF - Zeitschrift für Anorganische und Allgemeine Chemie

SN - 0044-2313

ER -