Bis(pyridine-2,6-dimethanol-N,O,O ')cobalt(II) and -copper(II) disaccharinate dihydrate: three-dimensional structures with extensive hydrogen bonds and aromatic pi-pi-stacking interactions

O Andac, S Guney, Y Topcu, V T Yilmaz, W T A Harrison

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21 Citations (Scopus)

Abstract

Bis(pyridine-2,6-dimethanol-N,O,O')cobalt(II) disaccharinate dihydrate, [Co(C7H9NO2)(2)](C7H4NO3S)(2).2H(2)O, (I), and bis(pyridine-2,6-dimethanol-N,O,O')copper(II) disaccharinate dihydrate, [Cu(C7H9NO2)(2)](C7H4NO3S)(2).2H(2)O, (II), collectively [M(dmpy)(2)](sac)(2).2H(2)O (where M is Co-II or Cu-II, sac is the saccharinate anion and dmpy is pyridine-2,6-dimethanol), are isostructural. The [M(dmpy)(2)](2+) cations exhibit distorted octahedral geometry in which the two neutral dmpy species act as tripodal N,O,O'-tridentate ligands. The crystal packing is determined by hydrogen bonding, as well as by weak pyridine-saccharinate pi-pi-stacking interactions.

Original languageEnglish
Number of pages4
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume58
DOIs
Publication statusPublished - 2002

Keywords

  • MOLECULAR-STRUCTURE
  • CRYSTAL

Cite this

@article{ac6568472f2c46b3b3fd8af29c70698c,
title = "Bis(pyridine-2,6-dimethanol-N,O,O ')cobalt(II) and -copper(II) disaccharinate dihydrate: three-dimensional structures with extensive hydrogen bonds and aromatic pi-pi-stacking interactions",
abstract = "Bis(pyridine-2,6-dimethanol-N,O,O')cobalt(II) disaccharinate dihydrate, [Co(C7H9NO2)(2)](C7H4NO3S)(2).2H(2)O, (I), and bis(pyridine-2,6-dimethanol-N,O,O')copper(II) disaccharinate dihydrate, [Cu(C7H9NO2)(2)](C7H4NO3S)(2).2H(2)O, (II), collectively [M(dmpy)(2)](sac)(2).2H(2)O (where M is Co-II or Cu-II, sac is the saccharinate anion and dmpy is pyridine-2,6-dimethanol), are isostructural. The [M(dmpy)(2)](2+) cations exhibit distorted octahedral geometry in which the two neutral dmpy species act as tripodal N,O,O'-tridentate ligands. The crystal packing is determined by hydrogen bonding, as well as by weak pyridine-saccharinate pi-pi-stacking interactions.",
keywords = "MOLECULAR-STRUCTURE, CRYSTAL",
author = "O Andac and S Guney and Y Topcu and Yilmaz, {V T} and Harrison, {W T A}",
year = "2002",
doi = "10.1107/S0108270101018807",
language = "English",
volume = "58",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",

}

TY - JOUR

T1 - Bis(pyridine-2,6-dimethanol-N,O,O ')cobalt(II) and -copper(II) disaccharinate dihydrate: three-dimensional structures with extensive hydrogen bonds and aromatic pi-pi-stacking interactions

AU - Andac, O

AU - Guney, S

AU - Topcu, Y

AU - Yilmaz, V T

AU - Harrison, W T A

PY - 2002

Y1 - 2002

N2 - Bis(pyridine-2,6-dimethanol-N,O,O')cobalt(II) disaccharinate dihydrate, [Co(C7H9NO2)(2)](C7H4NO3S)(2).2H(2)O, (I), and bis(pyridine-2,6-dimethanol-N,O,O')copper(II) disaccharinate dihydrate, [Cu(C7H9NO2)(2)](C7H4NO3S)(2).2H(2)O, (II), collectively [M(dmpy)(2)](sac)(2).2H(2)O (where M is Co-II or Cu-II, sac is the saccharinate anion and dmpy is pyridine-2,6-dimethanol), are isostructural. The [M(dmpy)(2)](2+) cations exhibit distorted octahedral geometry in which the two neutral dmpy species act as tripodal N,O,O'-tridentate ligands. The crystal packing is determined by hydrogen bonding, as well as by weak pyridine-saccharinate pi-pi-stacking interactions.

AB - Bis(pyridine-2,6-dimethanol-N,O,O')cobalt(II) disaccharinate dihydrate, [Co(C7H9NO2)(2)](C7H4NO3S)(2).2H(2)O, (I), and bis(pyridine-2,6-dimethanol-N,O,O')copper(II) disaccharinate dihydrate, [Cu(C7H9NO2)(2)](C7H4NO3S)(2).2H(2)O, (II), collectively [M(dmpy)(2)](sac)(2).2H(2)O (where M is Co-II or Cu-II, sac is the saccharinate anion and dmpy is pyridine-2,6-dimethanol), are isostructural. The [M(dmpy)(2)](2+) cations exhibit distorted octahedral geometry in which the two neutral dmpy species act as tripodal N,O,O'-tridentate ligands. The crystal packing is determined by hydrogen bonding, as well as by weak pyridine-saccharinate pi-pi-stacking interactions.

KW - MOLECULAR-STRUCTURE

KW - CRYSTAL

U2 - 10.1107/S0108270101018807

DO - 10.1107/S0108270101018807

M3 - Article

VL - 58

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -