Butane-1,4-diamine zinc(II) hydrogen phosphite

L K Ritchie, W T A Harrison

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The title compound, poly[zinc(II)-mu-butane-1,4-diamine-mu-( hydrogen phosphito)] (C4H12N2)(0.5)[ZnHPO3], is a hybrid organic - inorganic solid built up from 1,4-diaminobutane molecules, Zn2+ cations (coordinated by three O atoms and one N atom) and HPO32- hydrogen phosphite groups. The organic species bonds to the Zn atom as an unprotonated ligand, resulting in it acting as a bridge between infinite ZnHPO3 layers, which propagate in ( 100). The complete butane-1,4-diamine species is generated from a H2N(CH2)(2) - half molecule by inversion symmetry. The zincophosphite sheets contain polyhedral four- and eight-membered rings in a 4.8(2) topology.

Original languageEnglish
Number of pages3
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume60
DOIs
Publication statusPublished - 2004

Keywords

  • ZINCOPHOSPHITE
  • SELENITES

Cite this

Butane-1,4-diamine zinc(II) hydrogen phosphite. / Ritchie, L K ; Harrison, W T A .

In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. 60, 2004.

Research output: Contribution to journalArticle

@article{6b42f4449b4f4737a400722d6f9f5326,
title = "Butane-1,4-diamine zinc(II) hydrogen phosphite",
abstract = "The title compound, poly[zinc(II)-mu-butane-1,4-diamine-mu-( hydrogen phosphito)] (C4H12N2)(0.5)[ZnHPO3], is a hybrid organic - inorganic solid built up from 1,4-diaminobutane molecules, Zn2+ cations (coordinated by three O atoms and one N atom) and HPO32- hydrogen phosphite groups. The organic species bonds to the Zn atom as an unprotonated ligand, resulting in it acting as a bridge between infinite ZnHPO3 layers, which propagate in ( 100). The complete butane-1,4-diamine species is generated from a H2N(CH2)(2) - half molecule by inversion symmetry. The zincophosphite sheets contain polyhedral four- and eight-membered rings in a 4.8(2) topology.",
keywords = "ZINCOPHOSPHITE, SELENITES",
author = "Ritchie, {L K} and Harrison, {W T A}",
year = "2004",
doi = "10.1107/S0108270104024862",
language = "English",
volume = "60",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",

}

TY - JOUR

T1 - Butane-1,4-diamine zinc(II) hydrogen phosphite

AU - Ritchie, L K

AU - Harrison, W T A

PY - 2004

Y1 - 2004

N2 - The title compound, poly[zinc(II)-mu-butane-1,4-diamine-mu-( hydrogen phosphito)] (C4H12N2)(0.5)[ZnHPO3], is a hybrid organic - inorganic solid built up from 1,4-diaminobutane molecules, Zn2+ cations (coordinated by three O atoms and one N atom) and HPO32- hydrogen phosphite groups. The organic species bonds to the Zn atom as an unprotonated ligand, resulting in it acting as a bridge between infinite ZnHPO3 layers, which propagate in ( 100). The complete butane-1,4-diamine species is generated from a H2N(CH2)(2) - half molecule by inversion symmetry. The zincophosphite sheets contain polyhedral four- and eight-membered rings in a 4.8(2) topology.

AB - The title compound, poly[zinc(II)-mu-butane-1,4-diamine-mu-( hydrogen phosphito)] (C4H12N2)(0.5)[ZnHPO3], is a hybrid organic - inorganic solid built up from 1,4-diaminobutane molecules, Zn2+ cations (coordinated by three O atoms and one N atom) and HPO32- hydrogen phosphite groups. The organic species bonds to the Zn atom as an unprotonated ligand, resulting in it acting as a bridge between infinite ZnHPO3 layers, which propagate in ( 100). The complete butane-1,4-diamine species is generated from a H2N(CH2)(2) - half molecule by inversion symmetry. The zincophosphite sheets contain polyhedral four- and eight-membered rings in a 4.8(2) topology.

KW - ZINCOPHOSPHITE

KW - SELENITES

U2 - 10.1107/S0108270104024862

DO - 10.1107/S0108270104024862

M3 - Article

VL - 60

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -