Carbon-Monoxide Hydrogenation Over Metal Loaded Aluminophosphates

S T WONG, Russell Francis Howe, N B MILESTONE

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Abstract

This paper describes the preparation of molybdenum, cobalt and iron loaded ALP04- 5 catalysts via adsorption and decomposition of the corresponding carbonyl complexes. Mo (CO) 6 and Fe (CO) are adsorbed within the ALP04- 5 pores, and 30-50% of the transition metal is retained on subsequent activation. Co2 (CO)s adsorbs, and decomposes also on the external surface. The molybdenum-
and iron-loaded ALP04 - 5 catalysts show activities and selectivities in carbon monoxide hydrogenation similar to the corresponding zeolites. Broader product distributions from the cobalt loaded A1PO4- 5 are consistent with external loading, but this catalyst does not maintain a stable activity.
Original languageEnglish
Pages (from-to)229-242
Number of pages14
JournalApplied Catalysis A: General
Volume47
Issue number2
DOIs
Publication statusPublished - 15 Feb 1989

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