TY - JOUR
T1 - Catena-poly[[dihydraziniummanganese(II)]-di-mu-sulfato-kappa O-4 : O '] from synchrotron data
AU - Srinivasan, Krishnan
AU - Govindarajan, Subbaiah
AU - Harrison, William T. A.
PY - 2007/7
Y1 - 2007/7
N2 - The title compound, [Mn(N2H5)(2)(SO4)(2)](n), contains fairly regular trans-MnN2O4 octahedra. The Mn atoms (site symmetry 1) are bridged by pairs of sulfate groups into infinite [100] chains, which are cross-linked by a network of N - H center dot center dot center dot O hydrogen bonds arising from the hydrazinium groups. Mn(N2H5)(2)(SO4)(2) is isostructural with its iron, zinc, chromium and cadmium-containing analogues.
AB - The title compound, [Mn(N2H5)(2)(SO4)(2)](n), contains fairly regular trans-MnN2O4 octahedra. The Mn atoms (site symmetry 1) are bridged by pairs of sulfate groups into infinite [100] chains, which are cross-linked by a network of N - H center dot center dot center dot O hydrogen bonds arising from the hydrazinium groups. Mn(N2H5)(2)(SO4)(2) is isostructural with its iron, zinc, chromium and cadmium-containing analogues.
U2 - 10.1107/S1600536807024579
DO - 10.1107/S1600536807024579
M3 - Article
SN - 1600-5368
VL - 63
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 7
M1 - i152
ER -