Catena-poly[[dihydraziniummanganese(II)]-di-mu-sulfato-kappa O-4 : O '] from synchrotron data

Krishnan Srinivasan, Subbaiah Govindarajan, William T. A. Harrison

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Abstract

The title compound, [Mn(N2H5)(2)(SO4)(2)](n), contains fairly regular trans-MnN2O4 octahedra. The Mn atoms (site symmetry 1) are bridged by pairs of sulfate groups into infinite [100] chains, which are cross-linked by a network of N - H center dot center dot center dot O hydrogen bonds arising from the hydrazinium groups. Mn(N2H5)(2)(SO4)(2) is isostructural with its iron, zinc, chromium and cadmium-containing analogues.

Original languageEnglish
Article numberi152
Number of pages8
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number7
DOIs
Publication statusPublished - Jul 2007

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