Coloured products from thiopene and aromatic 1,2-diketones

W T A  Harrison; B J  Morrison; O C  Musgrave

doi:10.1016/j.tet.2004.07.066

Coloured products from thiopene and aromatic 1,2-diketones

W T A Harrison, B J Morrison, O C Musgrave

Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Thiophene and phenanthrene-9,10-quinone react in acidic solution to produce the deep blue extended quinone (Z,Z)-2,5-di(9-oxo-9,10-dihydro-10-phenanthrylidene)-2,5-dihydrothiophene the structure of which is confirmed by X-ray crystallography. Other aromatic 1,2-diketones give rise to related products. (C) 2004 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	9255-9262
Number of pages	8
Journal	Tetrahedron
Volume	60
Issue number	41
Early online date	26 Aug 2004
DOIs	https://doi.org/10.1016/j.tet.2004.07.066
Publication status	Published - 4 Oct 2004

Keywords

thiophene
diketones
quinone
X-ray crystal structure
condensations
constitution
indophenine

Access to Document

10.1016/j.tet.2004.07.066

Cite this

@article{655df579b83a481d9016d98eeef28762,

title = "Coloured products from thiopene and aromatic 1,2-diketones",

abstract = "Thiophene and phenanthrene-9,10-quinone react in acidic solution to produce the deep blue extended quinone (Z,Z)-2,5-di(9-oxo-9,10-dihydro-10-phenanthrylidene)-2,5-dihydrothiophene the structure of which is confirmed by X-ray crystallography. Other aromatic 1,2-diketones give rise to related products. (C) 2004 Elsevier Ltd. All rights reserved.",

keywords = "thiophene, diketones, quinone, X-ray crystal structure, condensations, constitution, indophenine",

author = "Harrison, {W T A} and Morrison, {B J} and Musgrave, {O C}",

year = "2004",

month = oct,

day = "4",

doi = "10.1016/j.tet.2004.07.066",

language = "English",

volume = "60",

pages = "9255--9262",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "PERGAMON-ELSEVIER SCIENCE LTD",

number = "41",

}

TY - JOUR

T1 - Coloured products from thiopene and aromatic 1,2-diketones

AU - Harrison, W T A

AU - Morrison, B J

AU - Musgrave, O C

PY - 2004/10/4

Y1 - 2004/10/4

N2 - Thiophene and phenanthrene-9,10-quinone react in acidic solution to produce the deep blue extended quinone (Z,Z)-2,5-di(9-oxo-9,10-dihydro-10-phenanthrylidene)-2,5-dihydrothiophene the structure of which is confirmed by X-ray crystallography. Other aromatic 1,2-diketones give rise to related products. (C) 2004 Elsevier Ltd. All rights reserved.

AB - Thiophene and phenanthrene-9,10-quinone react in acidic solution to produce the deep blue extended quinone (Z,Z)-2,5-di(9-oxo-9,10-dihydro-10-phenanthrylidene)-2,5-dihydrothiophene the structure of which is confirmed by X-ray crystallography. Other aromatic 1,2-diketones give rise to related products. (C) 2004 Elsevier Ltd. All rights reserved.

KW - thiophene

KW - diketones

KW - quinone

KW - X-ray crystal structure

KW - condensations

KW - constitution

KW - indophenine

U2 - 10.1016/j.tet.2004.07.066

DO - 10.1016/j.tet.2004.07.066

M3 - Article

VL - 60

SP - 9255

EP - 9262

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 41

ER -

Coloured products from thiopene and aromatic 1,2-diketones

Abstract

Keywords

Access to Document

Fingerprint

Cite this