Crystal structure of 4-azidomethyl-6-tert-butyl-2H-chromen-2-one

Nasseem El-Khatatneh; null Chandra; D. Shamala; K. Shivashankar; Mukhokosi Emma Panzi; M. Mahendra; W. T A Harrison

doi:10.1107/S205698901500290X

Crystal structure of 4-azidomethyl-6-tert-butyl-2H-chromen-2-one

Nasseem El-Khatatneh, Chandra, D. Shamala, K. Shivashankar, Mukhokosi Emma Panzi, M. Mahendra^*, W. T A Harrison (Editor)

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

In the title compound, C₁₄H₁₅N₃O₂, one of the methyl C atoms of the tert-butyl group lies almost in the plane of the chromene ring system [deviation = - 0.097 (2) Å], one lies above and one lies below [deviations = 1.460 (3) and 1.006 (3) Å, respectively]. The C - C - N - N torsion angle is 142.33 (17)°. In the crystal, moelcules are linked by weak C - H⋯O hydrogen bonds to generate C(6) chains propagating in the [010] direction.

Original language	English
Pages (from-to)	o218-o219
Number of pages	2
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	4
Early online date	4 Mar 2015
DOIs	https://doi.org/10.1107/S205698901500290X
Publication status	Published - 1 Apr 2015

Keywords

Chromene
Coumarin
Crystal structure
Hydrogen bonding

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10.1107/S205698901500290XLicence: CC BY

Crystal structure of 4-azidomethyl-6-tert-butyl-2H-chromen-2-one
© 2015 El-Khatatnehet al. Licence: Creative Commons Attribution (CC-BY) https://creativecommons.org/licenses/by/4.0
Final published version, 362 KBLicence: CC BY

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@article{16207148afe747c09ec1af47942d9d55,

title = "Crystal structure of 4-azidomethyl-6-tert-butyl-2H-chromen-2-one",

abstract = "In the title compound, C14H15N3O2, one of the methyl C atoms of the tert-butyl group lies almost in the plane of the chromene ring system [deviation = - 0.097 (2) {\AA}], one lies above and one lies below [deviations = 1.460 (3) and 1.006 (3) {\AA}, respectively]. The C - C - N - N torsion angle is 142.33 (17)°. In the crystal, moelcules are linked by weak C - H⋯O hydrogen bonds to generate C(6) chains propagating in the [010] direction.",

keywords = "Chromene, Coumarin, Crystal structure, Hydrogen bonding",

author = "Nasseem El-Khatatneh and Chandra and D. Shamala and K. Shivashankar and Panzi, {Mukhokosi Emma} and M. Mahendra and Harrison, {W. T A}",

note = "MM would like to thank UGC, New Delhi, Government of India, for the award of a project under the head F. No. 41–920/2012(SR) (dated: 25-07-2012). In addition, SD is thankful to the Council of Scientific and Industrial Research, New Delhi, India, for financial assistance [grant No. 02 (0172)/13/EMRII].",

year = "2015",

month = apr,

day = "1",

doi = "10.1107/S205698901500290X",

language = "English",

volume = "71",

pages = "o218--o219",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "4",

}

TY - JOUR

T1 - Crystal structure of 4-azidomethyl-6-tert-butyl-2H-chromen-2-one

AU - El-Khatatneh, Nasseem

AU - Chandra, null

AU - Shamala, D.

AU - Shivashankar, K.

AU - Panzi, Mukhokosi Emma

AU - Mahendra, M.

A2 - Harrison, W. T A

N1 - MM would like to thank UGC, New Delhi, Government of India, for the award of a project under the head F. No. 41–920/2012(SR) (dated: 25-07-2012). In addition, SD is thankful to the Council of Scientific and Industrial Research, New Delhi, India, for financial assistance [grant No. 02 (0172)/13/EMRII].

PY - 2015/4/1

Y1 - 2015/4/1

N2 - In the title compound, C14H15N3O2, one of the methyl C atoms of the tert-butyl group lies almost in the plane of the chromene ring system [deviation = - 0.097 (2) Å], one lies above and one lies below [deviations = 1.460 (3) and 1.006 (3) Å, respectively]. The C - C - N - N torsion angle is 142.33 (17)°. In the crystal, moelcules are linked by weak C - H⋯O hydrogen bonds to generate C(6) chains propagating in the [010] direction.

AB - In the title compound, C14H15N3O2, one of the methyl C atoms of the tert-butyl group lies almost in the plane of the chromene ring system [deviation = - 0.097 (2) Å], one lies above and one lies below [deviations = 1.460 (3) and 1.006 (3) Å, respectively]. The C - C - N - N torsion angle is 142.33 (17)°. In the crystal, moelcules are linked by weak C - H⋯O hydrogen bonds to generate C(6) chains propagating in the [010] direction.

KW - Chromene

KW - Coumarin

KW - Crystal structure

KW - Hydrogen bonding

UR - http://www.scopus.com/inward/record.url?scp=84928106904&partnerID=8YFLogxK

U2 - 10.1107/S205698901500290X

DO - 10.1107/S205698901500290X

M3 - Article

AN - SCOPUS:84928106904

VL - 71

SP - o218-o219

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 4

ER -

Crystal structure of 4-azidomethyl-6-tert-butyl-2H-chromen-2-one

Abstract

Keywords

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