Crystal structure of 4-[(E)-(4-nitro-benzylidene)amino]phenol

Zeliha Atioʇlu, Mehmet Akkurt*, Aliasghar Jarrahpour, Edris Ebrahimi, Orhan Büyükgüngör, W.T.A. Harrison (Editor)

*Corresponding author for this work

Research output: Contribution to journalArticle

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Abstract

The asymmetric unit of the title compound, C13H10N2O3, contains four independent molecules (I, II, III and IV). Molecule IV shows whole-molecule disorder over two sets of adjacent sites in a 0.669 (10):0.331 (10) ratio. The dihedral angles between the aromatic rings are 32.30 (13)° in molecule I, 2.24 (14)° in II, 41.61 (13)° in III, 5.0 (5)° in IV (major component) and 10.2 (3)° in IV (minor component). In the crystal, molecules are linked into layers lying parallel to (024) by C - H⋯O and O - H⋯O interactions. The layers interact by C - H⋯π and weak aromatic π-π stacking interactions [centroid-centroid distances = 3.8476 (16), 3.725 (3) and 3.733 (5) Å].

Original languageEnglish
Pages (from-to)o113-o114
Number of pages2
JournalActa Crystallographica Section E: Structure Reports Online
Volume71
Issue number2
Early online date17 Jan 2015
DOIs
Publication statusPublished - 1 Feb 2015

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Crystals
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Keywords

  • C - H⋯πinteractions
  • Crystal structure
  • Hydrogen bonding
  • Nitroaromatic compounds
  • Whole-molecule disorder
  • π-πstacking interactions

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

Crystal structure of 4-[(E)-(4-nitro-benzylidene)amino]phenol. / Atioʇlu, Zeliha; Akkurt, Mehmet; Jarrahpour, Aliasghar; Ebrahimi, Edris; Büyükgüngör, Orhan; Harrison, W.T.A. (Editor).

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 71, No. 2, 01.02.2015, p. o113-o114.

Research output: Contribution to journalArticle

Atioʇlu, Zeliha ; Akkurt, Mehmet ; Jarrahpour, Aliasghar ; Ebrahimi, Edris ; Büyükgüngör, Orhan ; Harrison, W.T.A. (Editor). / Crystal structure of 4-[(E)-(4-nitro-benzylidene)amino]phenol. In: Acta Crystallographica Section E: Structure Reports Online. 2015 ; Vol. 71, No. 2. pp. o113-o114.
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AU - Büyükgüngör, Orhan

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