Crystal structure of 4-methyl-N-[(4-methylpyridin-2-yl) carbamothioyl]benzamide

Farook Adam; Nadiah Ameram; Naser Eltaher Eltayeb; William Thomas Alexander Harrison

doi:10.1107/S2056989015003412

Crystal structure of 4-methyl-N-[(4-methylpyridin-2-yl) carbamothioyl]benzamide

Farook Adam, Nadiah Ameram, Naser Eltaher Eltayeb^*, William Thomas Alexander Harrison (Editor)

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

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Abstract

In the title compound, C₁₅H₁₅N₃OS, the dihedral angle between the planes of the benzene and pyridine rings is 26.86 (9)°. Intramolecular N - H⋯O and C - H⋯S hydrogen bonds both generate S(6) rings. The C=O and C=S bonds lie to opposite sides of the molecule. In the crystal, inversion dimers linked by pairs of N - H⋯S hydrogen bonds generate R²₂(8) loops.

Original language	English
Pages (from-to)	315-317
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	3
DOIs	https://doi.org/10.1107/S2056989015003412
Publication status	Published - 1 Mar 2015

Bibliographical note

The authors would like to thank Universiti Sains Malaysia for
a research grant (PKIMIA 846017), which partially supported
this work.

Keywords

Benzamide
Crystal structure
Hydrogen bonding
Thiocarbonyl groups
Thiourea compounds

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10.1107/S2056989015003412Licence: Other

Crystal structure of 4-methylFinal published version, 322 KBLicence: Other

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title = "Crystal structure of 4-methyl-N-[(4-methylpyridin-2-yl) carbamothioyl]benzamide",

abstract = "In the title compound, C15H15N3OS, the dihedral angle between the planes of the benzene and pyridine rings is 26.86 (9)°. Intramolecular N - H⋯O and C - H⋯S hydrogen bonds both generate S(6) rings. The C=O and C=S bonds lie to opposite sides of the molecule. In the crystal, inversion dimers linked by pairs of N - H⋯S hydrogen bonds generate R22(8) loops.",

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author = "Farook Adam and Nadiah Ameram and Eltayeb, {Naser Eltaher} and Harrison, {William Thomas Alexander}",

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T1 - Crystal structure of 4-methyl-N-[(4-methylpyridin-2-yl) carbamothioyl]benzamide

AU - Adam, Farook

AU - Ameram, Nadiah

AU - Eltayeb, Naser Eltaher

A2 - Harrison, William Thomas Alexander

N1 - The authors would like to thank Universiti Sains Malaysia for a research grant (PKIMIA 846017), which partially supported this work.

PY - 2015/3/1

Y1 - 2015/3/1

N2 - In the title compound, C15H15N3OS, the dihedral angle between the planes of the benzene and pyridine rings is 26.86 (9)°. Intramolecular N - H⋯O and C - H⋯S hydrogen bonds both generate S(6) rings. The C=O and C=S bonds lie to opposite sides of the molecule. In the crystal, inversion dimers linked by pairs of N - H⋯S hydrogen bonds generate R22(8) loops.

AB - In the title compound, C15H15N3OS, the dihedral angle between the planes of the benzene and pyridine rings is 26.86 (9)°. Intramolecular N - H⋯O and C - H⋯S hydrogen bonds both generate S(6) rings. The C=O and C=S bonds lie to opposite sides of the molecule. In the crystal, inversion dimers linked by pairs of N - H⋯S hydrogen bonds generate R22(8) loops.

KW - Benzamide

KW - Crystal structure

KW - Hydrogen bonding

KW - Thiocarbonyl groups

KW - Thiourea compounds

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

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ER -

Crystal structure of 4-methyl-N-[(4-methylpyridin-2-yl) carbamothioyl]benzamide

Abstract

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Keywords

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