Crystal structure of bis(thiourea-jS)bis(triphenyl-phosphane-κP)silver(I) nitrate

Sidra Nawaz, Muhammad Nawaz Tahir*, Muhammad Amir Nadeem, Bushra Mehmood, Saeed Ahmad, W. T A Harrison (Editor)

*Corresponding author for this work

Research output: Contribution to journalArticle

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Abstract

In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the AgI atom is coordinated by two thiourea S atoms and two triphenylphosphane P atoms in a distorted tetrahedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°. The Ag - S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C - H⋯O, C - H⋯S, N - H⋯O and N - H⋯S hydrogen bonds, generating (101¯) sheets.

Original languageEnglish
Pages (from-to)220-222
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume71
Issue number2
Early online date28 Jan 2015
DOIs
Publication statusPublished - 1 Feb 2015

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phosphine
Thiourea
Thioureas
thioureas
Silver
Nitrates
nitrates
Crystal structure
silver
Atoms
crystal structure
atoms
Hydrogen bonds
Salts
Ions
hydrogen bonds
salts
Crystals
Geometry
geometry

Keywords

  • Crystal structure
  • Hydrogen bonding
  • Silver(I) complex
  • Thiourea
  • Triphenyl-phosphane

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

Crystal structure of bis(thiourea-jS)bis(triphenyl-phosphane-κP)silver(I) nitrate. / Nawaz, Sidra; Tahir, Muhammad Nawaz; Nadeem, Muhammad Amir; Mehmood, Bushra; Ahmad, Saeed; Harrison, W. T A (Editor).

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 71, No. 2, 01.02.2015, p. 220-222.

Research output: Contribution to journalArticle

Nawaz, Sidra ; Tahir, Muhammad Nawaz ; Nadeem, Muhammad Amir ; Mehmood, Bushra ; Ahmad, Saeed ; Harrison, W. T A (Editor). / Crystal structure of bis(thiourea-jS)bis(triphenyl-phosphane-κP)silver(I) nitrate. In: Acta Crystallographica Section E: Structure Reports Online. 2015 ; Vol. 71, No. 2. pp. 220-222.
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