Crystal structure of bis(thiourea-jS)bis(triphenyl-phosphane-κP)silver(I) nitrate

Sidra Nawaz; Muhammad Nawaz Tahir; Muhammad Amir Nadeem; Bushra Mehmood; Saeed Ahmad; W. T A Harrison

doi:10.1107/S2056989015001395

Crystal structure of bis(thiourea-jS)bis(triphenyl-phosphane-κP)silver(I) nitrate

Sidra Nawaz, Muhammad Nawaz Tahir^*, Muhammad Amir Nadeem, Bushra Mehmood, Saeed Ahmad, W. T A Harrison (Editor)

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

10 Downloads (Pure)

Abstract

In the title salt, [Ag(CH₄N₂S)₂(PPh₃)₂]NO₃, the Ag^I atom is coordinated by two thiourea S atoms and two triphenylphosphane P atoms in a distorted tetrahedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°. The Ag - S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C - H⋯O, C - H⋯S, N - H⋯O and N - H⋯S hydrogen bonds, generating (101¯) sheets.

Original language	English
Pages (from-to)	220-222
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	2
Early online date	28 Jan 2015
DOIs	https://doi.org/10.1107/S2056989015001395
Publication status	Published - 1 Feb 2015

Bibliographical note

Acknowledgements
The authors acknowledge the provision of funds for the purchase of a diffractometer and encouragement by Dr Muhammad Akram Chaudhary, Vice Chancellor, University of Sargodha, Pakistan.

Keywords

Crystal structure
Hydrogen bonding
Silver(I) complex
Thiourea
Triphenyl-phosphane

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10.1107/S2056989015001395Licence: CC BY

Crystal structure of bis(thiourea-jS)bis(triphenylphosphane-jP)silver(I)nitrate
© 2015 Nawazet al. Licence: Creative Commons Attribution (CC-BY) https://creativecommons.org/licenses/by/4.0/
Final published version, 554 KBLicence: CC BY

Cite this

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title = "Crystal structure of bis(thiourea-jS)bis(triphenyl-phosphane-κP)silver(I) nitrate",

abstract = "In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the AgI atom is coordinated by two thiourea S atoms and two triphenylphosphane P atoms in a distorted tetrahedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°. The Ag - S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C - H⋯O, C - H⋯S, N - H⋯O and N - H⋯S hydrogen bonds, generating (101¯) sheets.",

keywords = "Crystal structure, Hydrogen bonding, Silver(I) complex, Thiourea, Triphenyl-phosphane",

author = "Sidra Nawaz and Tahir, {Muhammad Nawaz} and Nadeem, {Muhammad Amir} and Bushra Mehmood and Saeed Ahmad and Harrison, {W. T A}",

note = "Acknowledgements The authors acknowledge the provision of funds for the purchase of a diffractometer and encouragement by Dr Muhammad Akram Chaudhary, Vice Chancellor, University of Sargodha, Pakistan.",

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T1 - Crystal structure of bis(thiourea-jS)bis(triphenyl-phosphane-κP)silver(I) nitrate

AU - Nawaz, Sidra

AU - Tahir, Muhammad Nawaz

AU - Nadeem, Muhammad Amir

AU - Mehmood, Bushra

AU - Ahmad, Saeed

A2 - Harrison, W. T A

N1 - Acknowledgements The authors acknowledge the provision of funds for the purchase of a diffractometer and encouragement by Dr Muhammad Akram Chaudhary, Vice Chancellor, University of Sargodha, Pakistan.

PY - 2015/2/1

Y1 - 2015/2/1

N2 - In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the AgI atom is coordinated by two thiourea S atoms and two triphenylphosphane P atoms in a distorted tetrahedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°. The Ag - S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C - H⋯O, C - H⋯S, N - H⋯O and N - H⋯S hydrogen bonds, generating (101¯) sheets.

AB - In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the AgI atom is coordinated by two thiourea S atoms and two triphenylphosphane P atoms in a distorted tetrahedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°. The Ag - S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C - H⋯O, C - H⋯S, N - H⋯O and N - H⋯S hydrogen bonds, generating (101¯) sheets.

KW - Crystal structure

KW - Hydrogen bonding

KW - Silver(I) complex

KW - Thiourea

KW - Triphenyl-phosphane

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JO - Acta Crystallographica Section E: Structure Reports Online

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Crystal structure of bis(thiourea-jS)bis(triphenyl-phosphane-κP)silver(I) nitrate

Abstract

Bibliographical note

Keywords

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