Crystal structure of catena-poly[[tri-methyltin(IV)]-μ-2-(2-nitrophenyl)-acetato-κ2O:O′]

Muhammad Danish; Muhammad Nawaz Tahir; Sana Iftikhar; Muhammad Asam Raza; Muhammad Ashfaq; W. T A Harrison

doi:10.1107/S205698901500198X

Crystal structure of catena-poly[[tri-methyltin(IV)]-μ-2-(2-nitrophenyl)-acetato-κ²O:O′]

Muhammad Danish, Muhammad Nawaz Tahir^*, Sana Iftikhar, Muhammad Asam Raza, Muhammad Ashfaq, W. T A Harrison (Editor)

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

9 Downloads (Pure)

Abstract

In the title one-dimensional coordination polymer, [Sn(CH₃)₃(C₈H₆NO₄)]_n, the Sn^IV atom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC₃O₂ trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 2₁ screw axis. A weak π-π interaction exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å.

Original language	English
Pages (from-to)	m52-m53
Number of pages	2
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	3
Early online date	4 Feb 2015
DOIs	https://doi.org/10.1107/S205698901500198X
Publication status	Published - 1 Mar 2015

Bibliographical note

The authors acknowledge the provision of funds for the purchase of a diffractometer and encouragement by Dr Muhammad Akram Chaudhary, Vice Chancellor, University of Sargodha, Pakistan.

Keywords

Crystal structure
One-dimensional coordination polymer
Tri-methyltin(IV) complex
π-πInteraction

Access to Document

10.1107/S205698901500198XLicence: CC BY

crystal structure of catena-poly[[trimethyltin(IV)]-l-2-(2-nitrophenyl)-acetato-k2O:O']
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Final published version, 475 KBLicence: CC BY

Cite this

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title = "Crystal structure of catena-poly[[tri-methyltin(IV)]-μ-2-(2-nitrophenyl)-acetato-κ2O:O′]",

abstract = "In the title one-dimensional coordination polymer, [Sn(CH3)3(C8H6NO4)]n, the SnIV atom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC3O2 trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 21 screw axis. A weak π-π interaction exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) {\AA}.",

keywords = "Crystal structure, One-dimensional coordination polymer, Tri-methyltin(IV) complex, π-πInteraction",

author = "Muhammad Danish and Tahir, {Muhammad Nawaz} and Sana Iftikhar and Raza, {Muhammad Asam} and Muhammad Ashfaq and Harrison, {W. T A}",

note = "The authors acknowledge the provision of funds for the purchase of a diffractometer and encouragement by Dr Muhammad Akram Chaudhary, Vice Chancellor, University of Sargodha, Pakistan.",

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AU - Danish, Muhammad

AU - Tahir, Muhammad Nawaz

AU - Iftikhar, Sana

AU - Raza, Muhammad Asam

AU - Ashfaq, Muhammad

A2 - Harrison, W. T A

N1 - The authors acknowledge the provision of funds for the purchase of a diffractometer and encouragement by Dr Muhammad Akram Chaudhary, Vice Chancellor, University of Sargodha, Pakistan.

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N2 - In the title one-dimensional coordination polymer, [Sn(CH3)3(C8H6NO4)]n, the SnIV atom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC3O2 trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 21 screw axis. A weak π-π interaction exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å.

AB - In the title one-dimensional coordination polymer, [Sn(CH3)3(C8H6NO4)]n, the SnIV atom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC3O2 trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 21 screw axis. A weak π-π interaction exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å.

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