Crystal structure of catena-poly[[tri-methyltin(IV)]-μ-2-(2-nitrophenyl)-acetato-κ2O:O′]

Muhammad Danish; Muhammad Nawaz Tahir; Sana Iftikhar; Muhammad Asam Raza; Muhammad Ashfaq; W. T A Harrison

doi:10.1107/S205698901500198X

Crystal structure of catena-poly[[tri-methyltin(IV)]-μ-2-(2-nitrophenyl)-acetato-κ²O:O′]

Muhammad Danish, Muhammad Nawaz Tahir^*, Sana Iftikhar, Muhammad Asam Raza, Muhammad Ashfaq, W. T A Harrison (Editor)

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

In the title one-dimensional coordination polymer, [Sn(CH₃)₃(C₈H₆NO₄)]_n, the Sn^IV atom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC₃O₂ trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 2₁ screw axis. A weak π-π interaction exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å.

Original language	English
Pages (from-to)	m52-m53
Number of pages	2
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	3
Early online date	4 Feb 2015
DOIs	https://doi.org/10.1107/S205698901500198X
Publication status	Published - 1 Mar 2015

Keywords

Crystal structure
One-dimensional coordination polymer
Tri-methyltin(IV) complex
π-πInteraction

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10.1107/S205698901500198XLicence: CC BY

crystal structure of catena-poly[[trimethyltin(IV)]-l-2-(2-nitrophenyl)-acetato-k2O:O']
Copyright © Danish et al. 2015 This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. https://creativecommons.org/licenses/by/4.0
Final published version, 475 KBLicence: CC BY

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title = "Crystal structure of catena-poly[[tri-methyltin(IV)]-μ-2-(2-nitrophenyl)-acetato-κ2O:O′]",

abstract = "In the title one-dimensional coordination polymer, [Sn(CH3)3(C8H6NO4)]n, the SnIV atom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC3O2 trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 21 screw axis. A weak π-π interaction exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) {\AA}.",

keywords = "Crystal structure, One-dimensional coordination polymer, Tri-methyltin(IV) complex, π-πInteraction",

author = "Muhammad Danish and Tahir, {Muhammad Nawaz} and Sana Iftikhar and Raza, {Muhammad Asam} and Muhammad Ashfaq and Harrison, {W. T A}",

note = "The authors acknowledge the provision of funds for the purchase of a diffractometer and encouragement by Dr Muhammad Akram Chaudhary, Vice Chancellor, University of Sargodha, Pakistan.",

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AU - Danish, Muhammad

AU - Tahir, Muhammad Nawaz

AU - Iftikhar, Sana

AU - Raza, Muhammad Asam

AU - Ashfaq, Muhammad

A2 - Harrison, W. T A

N1 - The authors acknowledge the provision of funds for the purchase of a diffractometer and encouragement by Dr Muhammad Akram Chaudhary, Vice Chancellor, University of Sargodha, Pakistan.

PY - 2015/3/1

Y1 - 2015/3/1

N2 - In the title one-dimensional coordination polymer, [Sn(CH3)3(C8H6NO4)]n, the SnIV atom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC3O2 trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 21 screw axis. A weak π-π interaction exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å.

AB - In the title one-dimensional coordination polymer, [Sn(CH3)3(C8H6NO4)]n, the SnIV atom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC3O2 trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 21 screw axis. A weak π-π interaction exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å.

KW - Crystal structure

KW - One-dimensional coordination polymer

KW - Tri-methyltin(IV) complex

KW - π-πInteraction

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JO - Acta Crystallographica Section E: Structure Reports Online

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Crystal structure of catena-poly[[tri-methyltin(IV)]-μ-2-(2-nitrophenyl)-acetato-κ²O:O′]

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