Crystal structure of catena-poly[[tri-methyltin(IV)]-μ-2-(2-nitrophenyl)-acetato-κ2O:O′]

Muhammad Danish, Muhammad Nawaz Tahir*, Sana Iftikhar, Muhammad Asam Raza, Muhammad Ashfaq, W. T A Harrison (Editor)

*Corresponding author for this work

Research output: Contribution to journalArticle

1 Citation (Scopus)
5 Downloads (Pure)

Abstract

In the title one-dimensional coordination polymer, [Sn(CH3)3(C8H6NO4)]n, the SnIV atom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC3O2 trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 21 screw axis. A weak π-π interaction exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å.

Original languageEnglish
Pages (from-to)m52-m53
Number of pages2
JournalActa Crystallographica Section E: Structure Reports Online
Volume71
Issue number3
Early online date4 Feb 2015
DOIs
Publication statusPublished - 1 Mar 2015

Keywords

  • Crystal structure
  • One-dimensional coordination polymer
  • Tri-methyltin(IV) complex
  • π-πInteraction

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

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