Crystal structure of S-hexyl (E)-3-(4-methoxybenzylidene) dithiocarbazate

M. S. Begum; M.B.H. Howlader; R. Miyatake; E. Zangrando; M. C. Sheikh; W.T.A. Harrison

doi:10.1107/S2056989015003199

Crystal structure of S-hexyl (E)-3-(4-methoxybenzylidene) dithiocarbazate

M. S. Begum^*, M.B.H. Howlader, R. Miyatake, E. Zangrando, M. C. Sheikh, W.T.A. Harrison (Editor)

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

In the title compound, C₁₅H₂₂N₂OS₂, the dithiocarbazate group adopts an EE conformation with respect to the C=N bond of the benzylidene moiety. The hexyl side chain adopts an extended conformation and the C - S - C - C torsion angle is - 93.36 (13)°. In the crystal, inversion dimers linked by pairs of N - H⋯S hydrogen bonds generate R²₂(8) loops.

Original language	English
Pages (from-to)	o199-o199
Number of pages	1
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	3
Early online date	25 Feb 2015
DOIs	https://doi.org/10.1107/S2056989015003199
Publication status	Published - 1 Mar 2015

Keywords

Crystal structure
Dithiocarbazate
Hydrogen bonding
S-containing Schiff bases

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10.1107/S2056989015003199Licence: CC BY

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title = "Crystal structure of S-hexyl (E)-3-(4-methoxybenzylidene) dithiocarbazate",

abstract = "In the title compound, C15H22N2OS2, the dithiocarbazate group adopts an EE conformation with respect to the C=N bond of the benzylidene moiety. The hexyl side chain adopts an extended conformation and the C - S - C - C torsion angle is - 93.36 (13)°. In the crystal, inversion dimers linked by pairs of N - H⋯S hydrogen bonds generate R22(8) loops.",

keywords = "Crystal structure, Dithiocarbazate, Hydrogen bonding, S-containing Schiff bases",

author = "Begum, {M. S.} and M.B.H. Howlader and R. Miyatake and E. Zangrando and Sheikh, {M. C.} and W.T.A. Harrison",

note = "MBHH and MSB are grateful to the Department of Chemistry, Rajshahi University, for the provision of laboratory facilities. MCS acknowledges the Department of Applied Chemistry, Toyama University, for providing funds for single-crystal X-ray analyses.",

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T1 - Crystal structure of S-hexyl (E)-3-(4-methoxybenzylidene) dithiocarbazate

AU - Begum, M. S.

AU - Howlader, M.B.H.

AU - Miyatake, R.

AU - Zangrando, E.

AU - Sheikh, M. C.

A2 - Harrison, W.T.A.

N1 - MBHH and MSB are grateful to the Department of Chemistry, Rajshahi University, for the provision of laboratory facilities. MCS acknowledges the Department of Applied Chemistry, Toyama University, for providing funds for single-crystal X-ray analyses.

PY - 2015/3/1

Y1 - 2015/3/1

N2 - In the title compound, C15H22N2OS2, the dithiocarbazate group adopts an EE conformation with respect to the C=N bond of the benzylidene moiety. The hexyl side chain adopts an extended conformation and the C - S - C - C torsion angle is - 93.36 (13)°. In the crystal, inversion dimers linked by pairs of N - H⋯S hydrogen bonds generate R22(8) loops.

AB - In the title compound, C15H22N2OS2, the dithiocarbazate group adopts an EE conformation with respect to the C=N bond of the benzylidene moiety. The hexyl side chain adopts an extended conformation and the C - S - C - C torsion angle is - 93.36 (13)°. In the crystal, inversion dimers linked by pairs of N - H⋯S hydrogen bonds generate R22(8) loops.

KW - Crystal structure

KW - Dithiocarbazate

KW - Hydrogen bonding

KW - S-containing Schiff bases

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Crystal structure of S-hexyl (E)-3-(4-methoxybenzylidene) dithiocarbazate

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Keywords

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