Crystallisation of H3BTC, H3TPO or H(2)SDA with M-II (M = Co, Mn or Zn) and 2,2 '-bipyridyl: design and control of co-ordination architecture, and magnetic properties (H3BTC = benzene-1,3,5-tricarboxylic acid, H3TPO = tris(4-carboxylphenyl)phosphine oxide, H(2)SDA = cis-stilbene-4,4 '-dicarboxylic acid)

M J Plater, M R S Foreman, E Coronado, C J Gomez-Garcia, A M Z Slawin

Research output: Contribution to journalArticle

Abstract

The hydrothermal reaction of benzene-1,3,5-tricarboxylic acid (H3BTC) with M-II (M=Mn, Co or Zn), tris(4-carboxyphenyl)phosphine oxide (H3TPO) or cis-stilbene-4,4'-dicarboxylic acid (H(2)SDA) with Co-II and 2,2'-bipyridyl (BIPY) gave 1-D co-ordination networks formulated as: [M(HBTC)(BIPY)(H2O)] (M=Mn 1, Co 2, or Zn 3; [Co-3(BTC)(2)(BIPY)(2)(H2O)(6)]. 4H(2)O 4, [Co-3(TPO)(2)(BIPY)(2)(H2O)(6)]. xH(2)O 5 and [Co(SDA)(BIPY)(H2O)] 6. Structures 1 and 2 consist of double stranded chains of alternating HBTC dianions and dimeric units M-II-M-II linked by two mu-(1,1) bridging carboxylates. Magnetic properties of 1 and 2 indicate the presence of ferromagnetic exchange interactions within the dimers. Structures 4 and 5 consist of chains with a molecular ladder motif which are stacked creating large channels lined by hydrated cobalt(II) ions. The H2O/D2O solvent exchange in structure 5, studied by infrared spectroscopy and thermal gravimetric analysis-mass spectrometry, provides evidence for the porosity and zeolitic nature of the material.

Original languageEnglish
Pages (from-to)4209-4216
Number of pages8
JournalJournal of the Chemical Society, Dalton Transactions
Publication statusPublished - 1999

Keywords

  • METAL-ORGANIC FRAMEWORK
  • HYDROTHERMAL SYNTHESIS
  • CRYSTAL-STRUCTURE
  • TETRANUCLEAR COPPER(II)
  • POROUS SOLIDS
  • COMPLEXES
  • NETWORK
  • CHANNELS
  • PI
  • INTERPENETRATION

Cite this

@article{05f02bb87e384c3daeaa81e612241a4a,
title = "Crystallisation of H3BTC, H3TPO or H(2)SDA with M-II (M = Co, Mn or Zn) and 2,2 '-bipyridyl: design and control of co-ordination architecture, and magnetic properties (H3BTC = benzene-1,3,5-tricarboxylic acid, H3TPO = tris(4-carboxylphenyl)phosphine oxide, H(2)SDA = cis-stilbene-4,4 '-dicarboxylic acid)",
abstract = "The hydrothermal reaction of benzene-1,3,5-tricarboxylic acid (H3BTC) with M-II (M=Mn, Co or Zn), tris(4-carboxyphenyl)phosphine oxide (H3TPO) or cis-stilbene-4,4'-dicarboxylic acid (H(2)SDA) with Co-II and 2,2'-bipyridyl (BIPY) gave 1-D co-ordination networks formulated as: [M(HBTC)(BIPY)(H2O)] (M=Mn 1, Co 2, or Zn 3; [Co-3(BTC)(2)(BIPY)(2)(H2O)(6)]. 4H(2)O 4, [Co-3(TPO)(2)(BIPY)(2)(H2O)(6)]. xH(2)O 5 and [Co(SDA)(BIPY)(H2O)] 6. Structures 1 and 2 consist of double stranded chains of alternating HBTC dianions and dimeric units M-II-M-II linked by two mu-(1,1) bridging carboxylates. Magnetic properties of 1 and 2 indicate the presence of ferromagnetic exchange interactions within the dimers. Structures 4 and 5 consist of chains with a molecular ladder motif which are stacked creating large channels lined by hydrated cobalt(II) ions. The H2O/D2O solvent exchange in structure 5, studied by infrared spectroscopy and thermal gravimetric analysis-mass spectrometry, provides evidence for the porosity and zeolitic nature of the material.",
keywords = "METAL-ORGANIC FRAMEWORK, HYDROTHERMAL SYNTHESIS, CRYSTAL-STRUCTURE, TETRANUCLEAR COPPER(II), POROUS SOLIDS, COMPLEXES, NETWORK, CHANNELS, PI, INTERPENETRATION",
author = "Plater, {M J} and Foreman, {M R S} and E Coronado and Gomez-Garcia, {C J} and Slawin, {A M Z}",
year = "1999",
language = "English",
pages = "4209--4216",
journal = "Journal of the Chemical Society, Dalton Transactions",
issn = "1472-7773",

}

TY - JOUR

T1 - Crystallisation of H3BTC, H3TPO or H(2)SDA with M-II (M = Co, Mn or Zn) and 2,2 '-bipyridyl: design and control of co-ordination architecture, and magnetic properties (H3BTC = benzene-1,3,5-tricarboxylic acid, H3TPO = tris(4-carboxylphenyl)phosphine oxide, H(2)SDA = cis-stilbene-4,4 '-dicarboxylic acid)

AU - Plater, M J

AU - Foreman, M R S

AU - Coronado, E

AU - Gomez-Garcia, C J

AU - Slawin, A M Z

PY - 1999

Y1 - 1999

N2 - The hydrothermal reaction of benzene-1,3,5-tricarboxylic acid (H3BTC) with M-II (M=Mn, Co or Zn), tris(4-carboxyphenyl)phosphine oxide (H3TPO) or cis-stilbene-4,4'-dicarboxylic acid (H(2)SDA) with Co-II and 2,2'-bipyridyl (BIPY) gave 1-D co-ordination networks formulated as: [M(HBTC)(BIPY)(H2O)] (M=Mn 1, Co 2, or Zn 3; [Co-3(BTC)(2)(BIPY)(2)(H2O)(6)]. 4H(2)O 4, [Co-3(TPO)(2)(BIPY)(2)(H2O)(6)]. xH(2)O 5 and [Co(SDA)(BIPY)(H2O)] 6. Structures 1 and 2 consist of double stranded chains of alternating HBTC dianions and dimeric units M-II-M-II linked by two mu-(1,1) bridging carboxylates. Magnetic properties of 1 and 2 indicate the presence of ferromagnetic exchange interactions within the dimers. Structures 4 and 5 consist of chains with a molecular ladder motif which are stacked creating large channels lined by hydrated cobalt(II) ions. The H2O/D2O solvent exchange in structure 5, studied by infrared spectroscopy and thermal gravimetric analysis-mass spectrometry, provides evidence for the porosity and zeolitic nature of the material.

AB - The hydrothermal reaction of benzene-1,3,5-tricarboxylic acid (H3BTC) with M-II (M=Mn, Co or Zn), tris(4-carboxyphenyl)phosphine oxide (H3TPO) or cis-stilbene-4,4'-dicarboxylic acid (H(2)SDA) with Co-II and 2,2'-bipyridyl (BIPY) gave 1-D co-ordination networks formulated as: [M(HBTC)(BIPY)(H2O)] (M=Mn 1, Co 2, or Zn 3; [Co-3(BTC)(2)(BIPY)(2)(H2O)(6)]. 4H(2)O 4, [Co-3(TPO)(2)(BIPY)(2)(H2O)(6)]. xH(2)O 5 and [Co(SDA)(BIPY)(H2O)] 6. Structures 1 and 2 consist of double stranded chains of alternating HBTC dianions and dimeric units M-II-M-II linked by two mu-(1,1) bridging carboxylates. Magnetic properties of 1 and 2 indicate the presence of ferromagnetic exchange interactions within the dimers. Structures 4 and 5 consist of chains with a molecular ladder motif which are stacked creating large channels lined by hydrated cobalt(II) ions. The H2O/D2O solvent exchange in structure 5, studied by infrared spectroscopy and thermal gravimetric analysis-mass spectrometry, provides evidence for the porosity and zeolitic nature of the material.

KW - METAL-ORGANIC FRAMEWORK

KW - HYDROTHERMAL SYNTHESIS

KW - CRYSTAL-STRUCTURE

KW - TETRANUCLEAR COPPER(II)

KW - POROUS SOLIDS

KW - COMPLEXES

KW - NETWORK

KW - CHANNELS

KW - PI

KW - INTERPENETRATION

M3 - Article

SP - 4209

EP - 4216

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

SN - 1472-7773

ER -