Defining the role of substituents on adsorption and photocatalytic degradation of phenolic compounds

A. Tolosana-Moranchel, J. A. Anderson, J. A. Casas, M. Faraldos, A. Bahamonde*

*Corresponding author for this work

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The influence of adsorption behavior and the chemical nature of different para-positioned substituents was analyzed in the photocatalytic decomposition of phenol and other phenolic compounds (4-chlorophenol, 4-nitrophenol and methyl-p-hydroxybenzoato). Five commercial TiO2 photocatalysts, with differences in their physico-chemical properties, were selected for comparative purpose: P25 Aeroxide®, P25/20 VP Aeroperl® and P90 Aeroxide®, provided by Evonik Company, and UV 100 from Hombikak and PC 105 from Crystal Global. On the basis of adsorption isotherms it can be concluded that the maximum uptake of the different organic compounds are directly related to the specific surface area and surface acidity of the titania. Infrared spectroscopy in diffuse reflectance mode (DRIFTS) shows that the phenolic compounds are mainly adsorbed via interactions between the phenolic -OH group and TiO2 surface leading to formation of Ti-phenolates and Ti-OH. The photocatalytic removal of the phenolic compounds for the different titania samples does not follow a ranking based on the extent of adsorption whereas the initial photodegradation rate was strongly dependent on the chemical nature of the substituent, and could be correlated with the corresponding Hammett constant.

Original languageEnglish
Pages (from-to)4612-4620
Number of pages9
JournalJournal of Environmental Chemical Engineering
Volume5
Issue number5
Early online date5 Sep 2017
DOIs
Publication statusPublished - 1 Oct 2017

Fingerprint

phenolic compound
Titanium
adsorption
Adsorption
Degradation
degradation
titanium
Photodegradation
Photocatalysts
Phenol
Adsorption isotherms
Organic compounds
Acidity
Specific surface area
Chemical properties
Phenols
Infrared spectroscopy
chlorophenol
photodegradation
Decomposition

Keywords

  • Adsorption
  • DRIFTS
  • Hammett constant
  • Phenolic compounds
  • Photocatalysis
  • TiO

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Waste Management and Disposal
  • Pollution
  • Process Chemistry and Technology

Cite this

Defining the role of substituents on adsorption and photocatalytic degradation of phenolic compounds. / Tolosana-Moranchel, A.; Anderson, J. A.; Casas, J. A.; Faraldos, M.; Bahamonde, A.

In: Journal of Environmental Chemical Engineering, Vol. 5, No. 5, 01.10.2017, p. 4612-4620.

Research output: Contribution to journalArticle

Tolosana-Moranchel, A. ; Anderson, J. A. ; Casas, J. A. ; Faraldos, M. ; Bahamonde, A. / Defining the role of substituents on adsorption and photocatalytic degradation of phenolic compounds. In: Journal of Environmental Chemical Engineering. 2017 ; Vol. 5, No. 5. pp. 4612-4620.
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abstract = "The influence of adsorption behavior and the chemical nature of different para-positioned substituents was analyzed in the photocatalytic decomposition of phenol and other phenolic compounds (4-chlorophenol, 4-nitrophenol and methyl-p-hydroxybenzoato). Five commercial TiO2 photocatalysts, with differences in their physico-chemical properties, were selected for comparative purpose: P25 Aeroxide{\circledR}, P25/20 VP Aeroperl{\circledR} and P90 Aeroxide{\circledR}, provided by Evonik Company, and UV 100 from Hombikak and PC 105 from Crystal Global. On the basis of adsorption isotherms it can be concluded that the maximum uptake of the different organic compounds are directly related to the specific surface area and surface acidity of the titania. Infrared spectroscopy in diffuse reflectance mode (DRIFTS) shows that the phenolic compounds are mainly adsorbed via interactions between the phenolic -OH group and TiO2 surface leading to formation of Ti-phenolates and Ti-OH. The photocatalytic removal of the phenolic compounds for the different titania samples does not follow a ranking based on the extent of adsorption whereas the initial photodegradation rate was strongly dependent on the chemical nature of the substituent, and could be correlated with the corresponding Hammett constant.",
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