### Abstract

A non-intrusive technique has been developed for measuring agglomeration rate constants (beta(0)) in a constant shear field. A particulate suspension with a mean particle diameter, d, of about 10 mum is introduced in an optically accessible cylindrical Couette flow device. The suspension is illuminated by means of a pulsed laser and observed with a CCD camera. The recorded images are analysed off-line to determine the particle number concentration and a measure of the particle size. The time evolution of these quantities is fitted to an agglomeration rate law, from which the agglomeration rate constant is subsequently derived. By varying the rotational speed of the outer cylinder, different shear rates can be applied to the suspension. The full shear rate dependence of the agglomeration rate constant can be measured this way. Test results show that the set-up is well suited to determining particle concentrations, while only relative particle size information could be obtained. The measured signal shows a linear response to the suspension concentration and obeys the expected Poisson statistics. One set of agglomeration rate constants, measured at seven different shear rates between 15 and 55 s(-1) was obtained. A distinct maximum for beta(0) was found at a shear rate of 30 s(-1) which will be the subject of further study.

Original language | English |
---|---|

Article number | PII S0957-0233(02)32732-2 |

Pages (from-to) | 807-819 |

Number of pages | 13 |

Journal | Measurement Science and Technology |

Volume | 13 |

Issue number | 5 |

Publication status | Published - May 2002 |

### Keywords

- particle number concentration
- particle size
- Couette flow
- microscopy
- orthokinetic agglomeration
- industrial crystallization
- CALCIUM-OXALATE MONOHYDRATE
- AGGREGATION
- PRECIPITATION
- SHEAR

### Cite this

*Measurement Science and Technology*,

*13*(5), 807-819. [PII S0957-0233(02)32732-2].

**Developing a non-intrusive measuring technique for determining orthokinetic agglomeration rate constants.** / Hollander, ED; Derksen, JJ; Kramer, HJM; Van den Akker, HEA.

Research output: Contribution to journal › Article

*Measurement Science and Technology*, vol. 13, no. 5, PII S0957-0233(02)32732-2, pp. 807-819.

}

TY - JOUR

T1 - Developing a non-intrusive measuring technique for determining orthokinetic agglomeration rate constants

AU - Hollander, ED

AU - Derksen, JJ

AU - Kramer, HJM

AU - Van den Akker, HEA

PY - 2002/5

Y1 - 2002/5

N2 - A non-intrusive technique has been developed for measuring agglomeration rate constants (beta(0)) in a constant shear field. A particulate suspension with a mean particle diameter, d, of about 10 mum is introduced in an optically accessible cylindrical Couette flow device. The suspension is illuminated by means of a pulsed laser and observed with a CCD camera. The recorded images are analysed off-line to determine the particle number concentration and a measure of the particle size. The time evolution of these quantities is fitted to an agglomeration rate law, from which the agglomeration rate constant is subsequently derived. By varying the rotational speed of the outer cylinder, different shear rates can be applied to the suspension. The full shear rate dependence of the agglomeration rate constant can be measured this way. Test results show that the set-up is well suited to determining particle concentrations, while only relative particle size information could be obtained. The measured signal shows a linear response to the suspension concentration and obeys the expected Poisson statistics. One set of agglomeration rate constants, measured at seven different shear rates between 15 and 55 s(-1) was obtained. A distinct maximum for beta(0) was found at a shear rate of 30 s(-1) which will be the subject of further study.

AB - A non-intrusive technique has been developed for measuring agglomeration rate constants (beta(0)) in a constant shear field. A particulate suspension with a mean particle diameter, d, of about 10 mum is introduced in an optically accessible cylindrical Couette flow device. The suspension is illuminated by means of a pulsed laser and observed with a CCD camera. The recorded images are analysed off-line to determine the particle number concentration and a measure of the particle size. The time evolution of these quantities is fitted to an agglomeration rate law, from which the agglomeration rate constant is subsequently derived. By varying the rotational speed of the outer cylinder, different shear rates can be applied to the suspension. The full shear rate dependence of the agglomeration rate constant can be measured this way. Test results show that the set-up is well suited to determining particle concentrations, while only relative particle size information could be obtained. The measured signal shows a linear response to the suspension concentration and obeys the expected Poisson statistics. One set of agglomeration rate constants, measured at seven different shear rates between 15 and 55 s(-1) was obtained. A distinct maximum for beta(0) was found at a shear rate of 30 s(-1) which will be the subject of further study.

KW - particle number concentration

KW - particle size

KW - Couette flow

KW - microscopy

KW - orthokinetic agglomeration

KW - industrial crystallization

KW - CALCIUM-OXALATE MONOHYDRATE

KW - AGGREGATION

KW - PRECIPITATION

KW - SHEAR

M3 - Article

VL - 13

SP - 807

EP - 819

JO - Measurement Science and Technology

JF - Measurement Science and Technology

SN - 0957-0233

IS - 5

M1 - PII S0957-0233(02)32732-2

ER -