Di-tert-butylchlorido(pyrrolidine-1-dithiocarboxylato-kappa(2) S,S ') tin(IV)

Fahui Li, Yantuan Li, William T. A. Harrison, Weijie Wang, Yanping Feng

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The title compound, [Sn(C4H9)(2)(C5H8NS2)Cl], contains two molecules in the asymmetric unit, with similar conformations. In both molecules, the Sn atom adopts a distorted trigonal-bipyramidal geometry arising from two C atoms, one Cl atom and two S atoms from the bidentate dithiocarbamate ligand, with one Sn-S bond much longer than the other. One C atom of the pyrrolidine ring is disordered equally over two sites.

Original languageEnglish
Article numberm87
Number of pages13
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number1
DOIs
Publication statusPublished - Jan 2008

Keywords

  • crystal

Cite this

Di-tert-butylchlorido(pyrrolidine-1-dithiocarboxylato-kappa(2) S,S ') tin(IV). / Li, Fahui; Li, Yantuan; Harrison, William T. A.; Wang, Weijie; Feng, Yanping.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 64, No. 1, m87, 01.2008.

Research output: Contribution to journalArticle

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abstract = "The title compound, [Sn(C4H9)(2)(C5H8NS2)Cl], contains two molecules in the asymmetric unit, with similar conformations. In both molecules, the Sn atom adopts a distorted trigonal-bipyramidal geometry arising from two C atoms, one Cl atom and two S atoms from the bidentate dithiocarbamate ligand, with one Sn-S bond much longer than the other. One C atom of the pyrrolidine ring is disordered equally over two sites.",
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AU - Feng, Yanping

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N2 - The title compound, [Sn(C4H9)(2)(C5H8NS2)Cl], contains two molecules in the asymmetric unit, with similar conformations. In both molecules, the Sn atom adopts a distorted trigonal-bipyramidal geometry arising from two C atoms, one Cl atom and two S atoms from the bidentate dithiocarbamate ligand, with one Sn-S bond much longer than the other. One C atom of the pyrrolidine ring is disordered equally over two sites.

AB - The title compound, [Sn(C4H9)(2)(C5H8NS2)Cl], contains two molecules in the asymmetric unit, with similar conformations. In both molecules, the Sn atom adopts a distorted trigonal-bipyramidal geometry arising from two C atoms, one Cl atom and two S atoms from the bidentate dithiocarbamate ligand, with one Sn-S bond much longer than the other. One C atom of the pyrrolidine ring is disordered equally over two sites.

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