Diaquabis(biuretato-kappa O-2,O ')nickel(II) dichloride

J Lawson, W T A Harrison

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3 Citations (Scopus)

Abstract

The title compound, [Ni(C2H5N3O2)(2)(H2O)(2)]Cl-2, contains Ni2+ cations octahedrally coordinated by two bidentate biuret molecules in an O,O'-bidentate coordination mode and two water molecules, the latter in a trans configuration. Two chloride anions provide charge compensation. Numerous N-H...O (mean H...O = 2.17 Angstrom, mean N-H...O = 164degrees and mean N...O = 2.991 Angstrom), N - H...Cl (mean H...Cl = 2.46 Angstrom, mean N-H...Cl = 162degrees and mean N...Cl = 3.278 Angstrom) and O H...Cl (mean H...Cl = 2.19 Angstrom, mean O-H...Cl = 159degrees and mean O...Cl = 3.068 Angstrom) hydrogen bonds help to stabilize the crystal packing.

Original languageEnglish
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
DOIs
Publication statusPublished - 2005

Cite this

@article{873796ecc3f84d42b892547609a026ee,
title = "Diaquabis(biuretato-kappa O-2,O ')nickel(II) dichloride",
abstract = "The title compound, [Ni(C2H5N3O2)(2)(H2O)(2)]Cl-2, contains Ni2+ cations octahedrally coordinated by two bidentate biuret molecules in an O,O'-bidentate coordination mode and two water molecules, the latter in a trans configuration. Two chloride anions provide charge compensation. Numerous N-H...O (mean H...O = 2.17 Angstrom, mean N-H...O = 164degrees and mean N...O = 2.991 Angstrom), N - H...Cl (mean H...Cl = 2.46 Angstrom, mean N-H...Cl = 162degrees and mean N...Cl = 3.278 Angstrom) and O H...Cl (mean H...Cl = 2.19 Angstrom, mean O-H...Cl = 159degrees and mean O...Cl = 3.068 Angstrom) hydrogen bonds help to stabilize the crystal packing.",
author = "J Lawson and Harrison, {W T A}",
year = "2005",
doi = "10.1107/S1600536805004393",
language = "English",
volume = "61",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - Diaquabis(biuretato-kappa O-2,O ')nickel(II) dichloride

AU - Lawson, J

AU - Harrison, W T A

PY - 2005

Y1 - 2005

N2 - The title compound, [Ni(C2H5N3O2)(2)(H2O)(2)]Cl-2, contains Ni2+ cations octahedrally coordinated by two bidentate biuret molecules in an O,O'-bidentate coordination mode and two water molecules, the latter in a trans configuration. Two chloride anions provide charge compensation. Numerous N-H...O (mean H...O = 2.17 Angstrom, mean N-H...O = 164degrees and mean N...O = 2.991 Angstrom), N - H...Cl (mean H...Cl = 2.46 Angstrom, mean N-H...Cl = 162degrees and mean N...Cl = 3.278 Angstrom) and O H...Cl (mean H...Cl = 2.19 Angstrom, mean O-H...Cl = 159degrees and mean O...Cl = 3.068 Angstrom) hydrogen bonds help to stabilize the crystal packing.

AB - The title compound, [Ni(C2H5N3O2)(2)(H2O)(2)]Cl-2, contains Ni2+ cations octahedrally coordinated by two bidentate biuret molecules in an O,O'-bidentate coordination mode and two water molecules, the latter in a trans configuration. Two chloride anions provide charge compensation. Numerous N-H...O (mean H...O = 2.17 Angstrom, mean N-H...O = 164degrees and mean N...O = 2.991 Angstrom), N - H...Cl (mean H...Cl = 2.46 Angstrom, mean N-H...Cl = 162degrees and mean N...Cl = 3.278 Angstrom) and O H...Cl (mean H...Cl = 2.19 Angstrom, mean O-H...Cl = 159degrees and mean O...Cl = 3.068 Angstrom) hydrogen bonds help to stabilize the crystal packing.

U2 - 10.1107/S1600536805004393

DO - 10.1107/S1600536805004393

M3 - Article

VL - 61

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

ER -