Molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-dithiolato-S,S')plumbane, [Pb(C3S5)(C6H5)(2)], are linked into sheets via two intermolecular Pb . . .S-thione interactions of 3.322 (4) and 3.827 (4) Angstrom; the Pb centre has a distorted octahedral geometry. In contrast, molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-ithiolato-S,S')stannane, [Sn(C3S5)(C6H5)(2)], are linked into chains via a single intermolecular SnDSthione interaction of 2.8174 (9) Angstrom; the Sn centre has a distorted trigonal-bipyramidal geometry.
|Number of pages||3|
|Journal||Acta Crystallographica Section C, Crystal Structure Communications|
|Publication status||Published - 2001|