Diphenyl(2-thioxo-1,3-dithiole-4,5-di-thiolato-S,S ')plumbane at 295 K and diphenyl(2-thioxo-1,3-dithiole-4,5-di-thiolato-S,S ')stannane at 150 K

J M S Skakle, J L Wardell, S M S V Wardell

Research output: Contribution to journalArticle

Abstract

Molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-dithiolato-S,S')plumbane, [Pb(C3S5)(C6H5)(2)], are linked into sheets via two intermolecular Pb . . .S-thione interactions of 3.322 (4) and 3.827 (4) Angstrom; the Pb centre has a distorted octahedral geometry. In contrast, molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-ithiolato-S,S')stannane, [Sn(C3S5)(C6H5)(2)], are linked into chains via a single intermolecular SnDSthione interaction of 2.8174 (9) Angstrom; the Sn centre has a distorted trigonal-bipyramidal geometry.

Original languageEnglish
Pages (from-to)787-789
Number of pages3
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume57
Publication statusPublished - 2001

Keywords

  • CRYSTAL

Cite this

@article{edb19ac176db4e9faf67286e0f741247,
title = "Diphenyl(2-thioxo-1,3-dithiole-4,5-di-thiolato-S,S ')plumbane at 295 K and diphenyl(2-thioxo-1,3-dithiole-4,5-di-thiolato-S,S ')stannane at 150 K",
abstract = "Molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-dithiolato-S,S')plumbane, [Pb(C3S5)(C6H5)(2)], are linked into sheets via two intermolecular Pb . . .S-thione interactions of 3.322 (4) and 3.827 (4) Angstrom; the Pb centre has a distorted octahedral geometry. In contrast, molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-ithiolato-S,S')stannane, [Sn(C3S5)(C6H5)(2)], are linked into chains via a single intermolecular SnDSthione interaction of 2.8174 (9) Angstrom; the Sn centre has a distorted trigonal-bipyramidal geometry.",
keywords = "CRYSTAL",
author = "Skakle, {J M S} and Wardell, {J L} and Wardell, {S M S V}",
year = "2001",
language = "English",
volume = "57",
pages = "787--789",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",

}

TY - JOUR

T1 - Diphenyl(2-thioxo-1,3-dithiole-4,5-di-thiolato-S,S ')plumbane at 295 K and diphenyl(2-thioxo-1,3-dithiole-4,5-di-thiolato-S,S ')stannane at 150 K

AU - Skakle, J M S

AU - Wardell, J L

AU - Wardell, S M S V

PY - 2001

Y1 - 2001

N2 - Molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-dithiolato-S,S')plumbane, [Pb(C3S5)(C6H5)(2)], are linked into sheets via two intermolecular Pb . . .S-thione interactions of 3.322 (4) and 3.827 (4) Angstrom; the Pb centre has a distorted octahedral geometry. In contrast, molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-ithiolato-S,S')stannane, [Sn(C3S5)(C6H5)(2)], are linked into chains via a single intermolecular SnDSthione interaction of 2.8174 (9) Angstrom; the Sn centre has a distorted trigonal-bipyramidal geometry.

AB - Molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-dithiolato-S,S')plumbane, [Pb(C3S5)(C6H5)(2)], are linked into sheets via two intermolecular Pb . . .S-thione interactions of 3.322 (4) and 3.827 (4) Angstrom; the Pb centre has a distorted octahedral geometry. In contrast, molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-ithiolato-S,S')stannane, [Sn(C3S5)(C6H5)(2)], are linked into chains via a single intermolecular SnDSthione interaction of 2.8174 (9) Angstrom; the Sn centre has a distorted trigonal-bipyramidal geometry.

KW - CRYSTAL

M3 - Article

VL - 57

SP - 787

EP - 789

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -