Diphenyl(2-thioxo-1,3-dithiole-4,5-di-thiolato-S,S ')plumbane at 295 K and diphenyl(2-thioxo-1,3-dithiole-4,5-di-thiolato-S,S ')stannane at 150 K

J M S Skakle, J L Wardell, S M S V Wardell

Research output: Contribution to journalArticle

Abstract

Molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-dithiolato-S,S')plumbane, [Pb(C3S5)(C6H5)(2)], are linked into sheets via two intermolecular Pb . . .S-thione interactions of 3.322 (4) and 3.827 (4) Angstrom; the Pb centre has a distorted octahedral geometry. In contrast, molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-ithiolato-S,S')stannane, [Sn(C3S5)(C6H5)(2)], are linked into chains via a single intermolecular SnDSthione interaction of 2.8174 (9) Angstrom; the Sn centre has a distorted trigonal-bipyramidal geometry.

Original languageEnglish
Pages (from-to)787-789
Number of pages3
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume57
Publication statusPublished - 2001

Keywords

  • CRYSTAL

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