(E)-1-Phenyl-2-({5-[(1E)-(2-phenylhydrazin-1-ylidene)methyl]-2-thienyl}methylidene)hydrazine

Geraldo M. de Lima; William T. A. Harrison; Edward R. T. Tiekink; James L. Wardell; Solange M. S. V. Wardell

doi:10.1107/S1600536810003302

(E)-1-Phenyl-2-({5-[(1E)-(2-phenylhydrazin-1-ylidene)methyl]-2-thienyl}methylidene)hydrazine

Geraldo M. de Lima, William T. A. Harrison, Edward R. T. Tiekink, James L. Wardell, Solange M. S. V. Wardell

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title molecule, C18H16N4S, adopts a U-shape with the aromatic groups lying syn and orientated in the same direction as the thiophene S atom. The conformation about each of the C = N bonds is E. Overall, the molecule is curved as seen in the dihedral angle of 30.26 (19)degrees formed between the terminal benzene rings. In the crystal, supramolecular chains along the c axis are formed by a combination of N-H center dot center dot center dot N hydrogen bonds and N-H center dot center dot center dot pi interactions.

Original language	English
Pages (from-to)	o504-o505
Number of pages	2
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	3
DOIs	https://doi.org/10.1107/S1600536810003302
Publication status	Published - Mar 2010

Keywords

thiophene
hydrazones
series

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10.1107/S1600536810003302

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title = "(E)-1-Phenyl-2-({5-[(1E)-(2-phenylhydrazin-1-ylidene)methyl]-2-thienyl}methylidene)hydrazine",

abstract = "The title molecule, C18H16N4S, adopts a U-shape with the aromatic groups lying syn and orientated in the same direction as the thiophene S atom. The conformation about each of the C = N bonds is E. Overall, the molecule is curved as seen in the dihedral angle of 30.26 (19)degrees formed between the terminal benzene rings. In the crystal, supramolecular chains along the c axis are formed by a combination of N-H center dot center dot center dot N hydrogen bonds and N-H center dot center dot center dot pi interactions.",

keywords = "thiophene, hydrazones, series",

author = "{de Lima}, {Geraldo M.} and Harrison, {William T. A.} and Tiekink, {Edward R. T.} and Wardell, {James L.} and Wardell, {Solange M. S. V.}",

year = "2010",

month = mar,

doi = "10.1107/S1600536810003302",

language = "English",

volume = "66",

pages = "o504--o505",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "3",

}

TY - JOUR

T1 - (E)-1-Phenyl-2-({5-[(1E)-(2-phenylhydrazin-1-ylidene)methyl]-2-thienyl}methylidene)hydrazine

AU - de Lima, Geraldo M.

AU - Harrison, William T. A.

AU - Tiekink, Edward R. T.

AU - Wardell, James L.

AU - Wardell, Solange M. S. V.

PY - 2010/3

Y1 - 2010/3

N2 - The title molecule, C18H16N4S, adopts a U-shape with the aromatic groups lying syn and orientated in the same direction as the thiophene S atom. The conformation about each of the C = N bonds is E. Overall, the molecule is curved as seen in the dihedral angle of 30.26 (19)degrees formed between the terminal benzene rings. In the crystal, supramolecular chains along the c axis are formed by a combination of N-H center dot center dot center dot N hydrogen bonds and N-H center dot center dot center dot pi interactions.

AB - The title molecule, C18H16N4S, adopts a U-shape with the aromatic groups lying syn and orientated in the same direction as the thiophene S atom. The conformation about each of the C = N bonds is E. Overall, the molecule is curved as seen in the dihedral angle of 30.26 (19)degrees formed between the terminal benzene rings. In the crystal, supramolecular chains along the c axis are formed by a combination of N-H center dot center dot center dot N hydrogen bonds and N-H center dot center dot center dot pi interactions.

KW - thiophene

KW - hydrazones

KW - series

U2 - 10.1107/S1600536810003302

DO - 10.1107/S1600536810003302

M3 - Article

VL - 66

SP - o504-o505

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 3

ER -

(E)-1-Phenyl-2-({5-[(1E)-(2-phenylhydrazin-1-ylidene)methyl]-2-thienyl}methylidene)hydrazine

Abstract

Keywords

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